A novel hexanuclear silver(I) complex with photoluminescence properties

被引：12

作者：

Wu, Yining ^{[1
]}

Wu, Xuepeng ^{[1
]}

Fang, Sisi ^{[1
]}

Yang, Shuai ^{[1
]}

Li, Weitao ^{[1
]}

Wang, Huan ^{[3
]}

Yu, Xiaoxi ^{[2
]}

机构：

[1] China Univ Petr East China, Sch Petr Engn, Qingdao 266580, Shandong, Peoples R China

[2] China Univ Petr East China, Sch Chem Engn, Qingdao 266580, Shandong, Peoples R China

[3] China Univ Geosci, Sch Energy Resources, Beijing 100083, Peoples R China

来源：

POLYHEDRON | 2017年 / 122卷

关键词：

Silver complex; Crystal structure; Ag-Ag interaction; DFT calculation; Photoluminescence; CRYSTAL-STRUCTURE; LUMINESCENT PROPERTIES; LIGANDS; CLUSTER; METALLOLIGANDS; COPPER(I); FRAMEWORK; ACID;

D O I：

10.1016/j.poly.2016.08.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A hexanuclear complex of d(10)-d(10) transition metal with organosulfur ligand, Ag-6(py2t)(6) (py2t = pyrazine-2-thiol), has been synthesized using diffusion methodology at room temperature. Crystal structure was revealed using single crystal X-ray diffraction and data indicate that the complex synthesized containing Ag-Ag bonds in the silver cluster. The density function theory (DFT) calculation was performed to investigate the molecular orbital and photoluminescence potential. The photoluminescence properties of the complex have been further investigated, and a favorable fluorescence property was observed from the complex. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：155 / 160

页数：6

共 50 条

[41] Syntheses, structural characterization, and antibacterial properties of a hexanuclear bimetallic cluster complex
G. L. Zhang
L. Ran
X. Q. Luo
R. G. Hu
J. Zeng
Russian Journal of Coordination Chemistry, 2013, 39 : 792 - 797
[42] Syntheses, structural characterization, and antibacterial properties of a hexanuclear bimetallic cluster complex
Zhang, G. L.
Ran, L.
Luo, X. Q.
Hu, R. G.
Zeng, J.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2013, 39 (11) : 792 - 797
[43] Synthesis, crystal structure, and luminescent properties of a silver(I) perrhenate complex with phenazine
Kokunov, Yu. V.
Gorbunova, Yu. E.
Kovalev, V. V.
Kozyukhin, S. A.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 58 (05) : 523 - 526
[44] DFT Calculations on Spectroscopic, Structural and NLO Properties of Silver (I) Complex with Picolinamide
Alturk, Sumeyye
Avci, Davut
Tamer, Omer
Atalay, Yusuf
PROCEEDINGS OF THE TURKISH PHYSICAL SOCIETY 32ND INTERNATIONAL PHYSICS CONGRESS (TPS32), 2017, 1815
[45] Synthesis, crystal structure, and luminescent properties of a silver(I) perrhenate complex with phenazine
Yu. V. Kokunov
Yu. E. Gorbunova
V. V. Kovalev
S. A. Kozyukhin
Russian Journal of Inorganic Chemistry, 2013, 58 : 523 - 526
[46] Synthesis, structure and photoluminescence properties of silver(I) coordination polymers with bis(4-pyridyl)benzylamine
Shin, Jong Won
Cho, Hyun Jung
Min, Kil Sik
INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 16 : 12 - 16
[47] Anion-Controlled Assembly of Silver(I)/Aminobenzonitrile Compounds: Syntheses, Crystal Structures, and Photoluminescence Properties
Liu, Fu-Jing
Sun, Di
Hao, Hong-Jun
Huang, Rong-Bin
Zheng, Lan-Sun
CRYSTAL GROWTH & DESIGN, 2012, 12 (01) : 354 - 361
[48] Photoluminescence Properties, Molecular Structures, and Theoretical Study of Heteroleptic Silver(I) Complexes Containing Diphosphine Ligands
Igawa, Satoshi
Hashimoto, Masashi
Kawata, Isao
Hoshino, Mikio
Osawa, Masahisa
INORGANIC CHEMISTRY, 2012, 51 (10) : 5805 - 5813
[49] A Silver(I)–Gold(II) Hexanuclear Guanidinate–Benzoate Cluster with Short Au–Au Bonds
Ahmed A. Mohamed
Hanan E. Abdou
Andrew Mayer
John P. Fackler
Journal of Cluster Science, 2008, 19 : 551 - 559
[50] Novel polymeric potassium complex: Its synthesis, structural characterization, photoluminescence and electrochemical properties
Ceyhan, Gokhan
Tumer, Mehmet
Koese, Muhammet
McKee, Vickie
JOURNAL OF LUMINESCENCE, 2012, 132 (03) : 850 - 857

← 1 2 3 4 5 →