A novel hexanuclear silver(I) complex with photoluminescence properties

被引：12

作者：

Wu, Yining ^{[1
]}

Wu, Xuepeng ^{[1
]}

Fang, Sisi ^{[1
]}

Yang, Shuai ^{[1
]}

Li, Weitao ^{[1
]}

Wang, Huan ^{[3
]}

Yu, Xiaoxi ^{[2
]}

机构：

[1] China Univ Petr East China, Sch Petr Engn, Qingdao 266580, Shandong, Peoples R China

[2] China Univ Petr East China, Sch Chem Engn, Qingdao 266580, Shandong, Peoples R China

[3] China Univ Geosci, Sch Energy Resources, Beijing 100083, Peoples R China

来源：

POLYHEDRON | 2017年 / 122卷

关键词：

Silver complex; Crystal structure; Ag-Ag interaction; DFT calculation; Photoluminescence; CRYSTAL-STRUCTURE; LUMINESCENT PROPERTIES; LIGANDS; CLUSTER; METALLOLIGANDS; COPPER(I); FRAMEWORK; ACID;

D O I：

10.1016/j.poly.2016.08.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A hexanuclear complex of d(10)-d(10) transition metal with organosulfur ligand, Ag-6(py2t)(6) (py2t = pyrazine-2-thiol), has been synthesized using diffusion methodology at room temperature. Crystal structure was revealed using single crystal X-ray diffraction and data indicate that the complex synthesized containing Ag-Ag bonds in the silver cluster. The density function theory (DFT) calculation was performed to investigate the molecular orbital and photoluminescence potential. The photoluminescence properties of the complex have been further investigated, and a favorable fluorescence property was observed from the complex. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：155 / 160

页数：6

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