Spectroscopic studies of electrochemically doped polyindole

被引：29
|
作者：
Talbi, H
Maarouf, EB
Humbert, B
Alnot, M
Ehrhardt, JJ
Ghanbaja, J
Billaud, D
机构：
[1] UNIV MOHAMMED 1ER,LAB CHIM ANALYT APPL,OUJDA,MOROCCO
[2] CNRS,UHP,LAB CHIM PHYS ENVIRONM,F-54600 VILLERS LES NANCY,FRANCE
来源：
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 1996年 / 57卷 / 6-8期
关键词：
electronic materials; polymers; electron energy loss spectroscopy (EELS); infrared spectroscopy; photoelectron spectroscopy;
D O I：
10.1016/0022-3697(95)00413-0
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The electro-oxidation of indole, C8NH7, in LiClO4-acetonitrile solution, leads to the formation of an electroactive polymer. This compound, in the doped state, was characterized by PEELS, XPS and FTIR spectroscopies. The sites of polymerization do not involve the benzene ring, but are rather on the 1 and 3 positions of the pyrrole ring. The most probable structure of ClO4--doped polyindole is a regular alternance of 1,1-3,3 couplings.
引用
收藏
页码：1145 / 1151
页数：7
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