Imines, enamines and oximes

被引：225

作者：

Adams, JP ^{[1
]}

机构：

[1] Glaxo Wellcome Res & Dev Ltd, Med Res Ctr, Stevenage SG1 2NY, Herts, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2000年 / 02期

关键词：

D O I：

10.1039/a808142e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Imines, enamines and oximes were discussed. Imines were formed by the action of catalytic scandium or lanthanide triflates on a mixture of acetals and primary amines in toluene with molecular sieves in 41-96% yields. Aldehydes and ketones reacted with primary amines to give imines in 80-97% yields by using microwave irradiation with envirocat EPZG(R) as a catalyst under solvent free conditions. Results showed that oximes were conveniently converted into nitroalkanes using oxone in acetonitrile, buffered at pH 7.5.

引用

页码：125 / 139

页数：15

共 50 条

[31] Direct conversion of esters to imines/enamines and applications to polyester waste upcycling
Kehner, Rebecca A.
Huang, Weiheng
Bayeh-Romero, Liela
CHEMICAL SCIENCE, 2024, 15 (41) : 16947 - 16953
[32] α-thiosubstituted chiral imines/secondary enamines:: their use in the asymmetric Michael reaction
Nour, M
Tan, K
Cavé, C
Villeneuve, D
Desmaële, D
d'Angelo, J
Riche, C
TETRAHEDRON-ASYMMETRY, 2000, 11 (04) : 995 - 1002
[33] Reaction of N-Sulfonyl-1,4-benzoquinone Imines with Enamines
Konovalova, S. A.
Avdeenko, A. P.
Pirozhenko, V. V.
Yusina, A. L.
Palamarchuk, G. V.
Shishkina, S. V.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 53 (04) : 525 - 538
[34] GENERATION OF VINYL CATIONS BY NITROSATION OF N-SILYLATED IMINES AND ENAMINES
ALVAREZ, RM
HANACK, M
SUBRAMANIAN, LR
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1993, 6 (01) : 44 - 46
[35] Reaction of N-sulfonyl-1,4-benzoquinone imines with enamines
S. A. Konovalova
A. P. Avdeenko
V. V. Pirozhenko
A. L. Yusina
G. V. Palamarchuk
S. V. Shishkina
Russian Journal of Organic Chemistry, 2017, 53 : 525 - 538
[36] Metal-free catalytic hydrogenation of enamines, imines, and conjugated phosphinoalkenylboranes
Spies, Patrick
Schwendemann, Sina
Lange, Stefanie
Kehr, Gerald
Froehlich, Roland
Erker, Gerhard
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (39) : 7543 - 7546
[37] Transdithioacetalization of acetals, ketals, oximes, enamines and tosylhydrazones catalysed by natural kaolinitic clay
Jnaneshwara, GK
Barhate, NB
Sudalai, A
Deshpande, VH
Wakharkar, RD
Gajare, AS
Shingare, MS
Sukumar, R
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (05): : 965 - 968
[38] Butyltriphenylphosphonium tetraborate (BTPPTB) as a selective reducing agent for the reduction of imines, enamines and oximes and reductive alkylation of aldehydes or ketones with primary amines in methanol or under solid-phase conditions
Hajipour, AR
Mohammadpoor-Baltork, I
Noroallhi, M
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2001, 40 (02): : 152 - 156
[39] Synthesis of 2-aminotropone oximes and 2-alkoxytropone imines
Nozoe, T
Lin, LC
Hsu, CH
Tsay, SC
Hakimelahi, GH
Hwu, JR
JOURNAL OF CHEMICAL RESEARCH-S, 1997, (10): : 362 - 363
[40] Unexpected but prominent imines formation in Beckmann rearrangement of (spiro)pyranocoumarin oximes
Krasylov, Igor V.
Moskvina, Viktoriia S.
Khilya, Volodymyr P.
TETRAHEDRON LETTERS, 2023, 129

← 1 2 3 4 5 →