Imines, enamines and oximes

被引：225

作者：

Adams, JP ^{[1
]}

机构：

[1] Glaxo Wellcome Res & Dev Ltd, Med Res Ctr, Stevenage SG1 2NY, Herts, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2000年 / 02期

关键词：

D O I：

10.1039/a808142e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Imines, enamines and oximes were discussed. Imines were formed by the action of catalytic scandium or lanthanide triflates on a mixture of acetals and primary amines in toluene with molecular sieves in 41-96% yields. Aldehydes and ketones reacted with primary amines to give imines in 80-97% yields by using microwave irradiation with envirocat EPZG(R) as a catalyst under solvent free conditions. Results showed that oximes were conveniently converted into nitroalkanes using oxone in acetonitrile, buffered at pH 7.5.

引用

页码：125 / 139

页数：15

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