Two type skeleton heterobimetallic trinuclear Cu-Mo-S clusters containing closo carborane diphosphine ligand 1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane

被引：9

作者：

Dou, Jianmin ^{[1
]}

Zhang, Daopeng ^{[1
]}

Li, Dacheng ^{[1
]}

Wang, Daqi ^{[1
]}

机构：

[1] Liaocheng Univ, Dept Chem, Liaocheng 252059, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 11期

基金：

中国国家自然科学基金;

关键词：

synthesis and characterization; crystal structure; Cu-Mo-S cluster; 1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane;

D O I：

10.1016/j.inoche.2006.07.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The carborane skeleton was introduced into the heterometallic sulfide cluster cores. Two heterobimetallic trinuclear Cu-Mo-S clusters with linear or butterfly-shaped skeleton containing 1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane have been synthesized by the reactions of (NH4)(2)MoS4 or (NH4)(2)MoOS3, CuSCN with 1,2-(PPh2)(2)-1,2-C2B10H10 (L) in dichloromethane and characterized by elemental analysis, FT-IR, UV/Visible, H-1 and C-13 NMR spectroscopy and X-ray structure determination. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：1099 / 1102

页数：4

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