Di-μ-chlorido-bis{[1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane-k2P,P′]silver(I)}dichloromethane disolvate

被引：7
|
作者：
Zhang, Dao-Peng [1 ]
Dou, Jian-Min [1 ]
Li, Da-Cheng [1 ]
Wang, Da-Qi [1 ]
机构：
[1] Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252059, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807007088
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [ Ag2Cl2( C26H30B10P2)(2)]center dot 2CH(2)Cl(2), was synthesized by the reaction of 1,2-bis( dipenylphosphino)-1,2-dicarba-closo-dodecaborane with AgCl in ethanol. The diphosphino-closo-carborane ligand is coordinated in a bidentate manner to the Ag atom through the two P atoms. The coordination of the Ag atom is distorted tetrahedral, in which two vertices are formed by one chelating diphosphine ligand, and the other two are occupied by two bridging Cl atoms. The molecule is centrosymmetric.
引用
收藏
页码：M1086 / M1088
页数：3
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