Synthesis of Polycyclic Natural Products through Skeletal Rearrangement

被引:7
|
作者
Yokoshima, Satoshi [1 ]
机构
[1] Nagoya Univ, Grad Sch Pharmaceut Sci, Chikusa Ku, Furo Cho, Nagoya, Aichi 4648601, Japan
基金
日本学术振兴会;
关键词
alkaloids; cycloaddition; natural products; rearrangement; total synthesis; DIVERGENT TOTAL SYNTHESES; DIELS-ALDER REACTIONS; LYCOPODIUM ALKALOIDS; (-)-HUPERZINE Q; HUPERZINE-R; METATHESIS; LYCONADINS; DEAROMATIZATION;
D O I
10.1055/s-0040-1707904
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Construction of rings through reliable reactions followed by changes in the ring size or the connectivity through skeletal rearrangement provides molecules with a wide range of skeletons. In this account, our syntheses of polycyclic natural products through skeletal rearrangement are discussed. Introduction Synthesis through Changes in the Ring Size Synthesis by Biomimetic Strategies Synthesis through Metathesis Synthesis through Temporary Formation of a Ring Conclusion
引用
收藏
页码:1967 / 1975
页数:9
相关论文
共 50 条
  • [41] BENZENOID AND POLYCYCLIC AROMATIC NATURAL-PRODUCTS
    SIMPSON, TJ
    NATURAL PRODUCT REPORTS, 1987, 4 (06) : 639 - 676
  • [42] Total Synthesis of Polycyclic Natural Products via Photoenolization/Diels-Alder Reaction
    Yang, Baochao
    Hou, Min
    Gao, Shuanhu
    ACCOUNTS OF CHEMICAL RESEARCH, 2025,
  • [43] Biomimetic Synthesis of Polycyclic Polyprenylated Acylphloroglucinol Natural Products Isolated from Hypericum papuanum
    George, Jonathan H.
    Hesse, Micha D.
    Baldwin, Jack E.
    Adlington, Robert M.
    ORGANIC LETTERS, 2010, 12 (15) : 3532 - 3535
  • [45] Some recent advances in the synthesis of polycyclic imidazole-containing marine natural products
    Weinreb, Steven M.
    NATURAL PRODUCT REPORTS, 2007, 24 (05) : 931 - 948
  • [46] The Claisen rearrangement in the syntheses of bioactive natural products
    Majumdar, K. C.
    Nandi, Raj Kumar
    TETRAHEDRON, 2013, 69 (34) : 6921 - 6957
  • [47] APPLICATION OF THE AZA-CLAISEN REARRANGEMENT TO THE TOTAL SYNTHESIS OF NATURAL-PRODUCTS - (-)-ISOIRIDOMYRMECIN
    ITO, S
    TSUNODA, T
    PURE AND APPLIED CHEMISTRY, 1994, 66 (10-11) : 2071 - 2074
  • [48] The natural rearrangement invariant structure on tensor products
    Fernandez-Gonzalez, C.
    Palazuelos, C.
    Perez-Garcia, D.
    JOURNAL OF MATHEMATICAL ANALYSIS AND APPLICATIONS, 2008, 343 (01) : 40 - 47
  • [49] Natural products and skeletal muscle health
    Qu, Zhihao
    Zhou, Shiyu
    Li, Penghui
    Liu, Changwei
    Yuan, Bin
    Zhang, Sheng
    Liu, Ailing
    JOURNAL OF NUTRITIONAL BIOCHEMISTRY, 2021, 93
  • [50] Synthesis of a Potent Antimalarial Agent through Natural Products Conjugation
    Bruno, Michela
    Trucchi, Beatrice
    Monti, Diego
    Romeo, Sergio
    Kaiser, Marcel
    Verotta, Luisella
    CHEMMEDCHEM, 2013, 8 (02) : 221 - 225