Synthesis of Polycyclic Natural Products through Skeletal Rearrangement

被引：7
|
作者：
Yokoshima, Satoshi [1 ]
机构：
[1] Nagoya Univ, Grad Sch Pharmaceut Sci, Chikusa Ku, Furo Cho, Nagoya, Aichi 4648601, Japan
来源：
SYNLETT | 2020年 / 31卷 / 20期
基金：
日本学术振兴会;
关键词：
alkaloids; cycloaddition; natural products; rearrangement; total synthesis; DIVERGENT TOTAL SYNTHESES; DIELS-ALDER REACTIONS; LYCOPODIUM ALKALOIDS; (-)-HUPERZINE Q; HUPERZINE-R; METATHESIS; LYCONADINS; DEAROMATIZATION;
D O I：
10.1055/s-0040-1707904
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Construction of rings through reliable reactions followed by changes in the ring size or the connectivity through skeletal rearrangement provides molecules with a wide range of skeletons. In this account, our syntheses of polycyclic natural products through skeletal rearrangement are discussed. Introduction Synthesis through Changes in the Ring Size Synthesis by Biomimetic Strategies Synthesis through Metathesis Synthesis through Temporary Formation of a Ring Conclusion
引用
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页码：1967 / 1975
页数：9
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