Synthesis structure, and transition metal complexes of amphiphilic 1,5-diaza-3,7-diphosphacyclooctanes

被引：42

作者：

Karasik, Andrey A.

Naumov, Roman N.

Balueva, Anna S.

Spiridonova, Yulia S.

Golodkov, Oleg N.

Novikova, Helen V.

Belov, Gennadii P.

Katsyuba, Sergey A.

Vandyukova, Elena E.

Lonnecke, Peter

Hey-Hawkins, Evamarie

Sinyashin, Oleg G.

机构：

[1] Russian Acad Sci, AE Arbuzov Organ & Phys Chem Inst, Kazan Sci Ctr, Kazan 420088, Russia

[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow, Russia

[3] Univ Leipzig, Inst Anorgan Chem, D-04103 Leipzig, Germany

来源：

HETEROATOM CHEMISTRY | 2006年 / 17卷 / 06期

关键词：

D O I：

10.1002/hc.20272

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Amphiphilic 1,5-diaza-3,7-diphosphacyclooctanes have been synthesized by condensation of hydrophobic primary arylphosphines, formaldehyde, and functionalized hydrophilic primary arylamines (5-aminoisophthalic acid and the sodium salt of sulfanilic acid). These compounds readily form P,P-chelate complexes with [PtCl2(cod)], which are stable in water. The catalytic activity of palladium catalysts with 1, 5-diaza-3,7-diphosphacyclooctane ligands was studied in the copolymerization of ethylene and carbon monoxide. (c) 2006 Wiley Periodicals, Inc.

引用

页码：499 / 513

页数：15

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