Synthesis structure, and transition metal complexes of amphiphilic 1,5-diaza-3,7-diphosphacyclooctanes

被引：42
|
作者：
Karasik, Andrey A.
Naumov, Roman N.
Balueva, Anna S.
Spiridonova, Yulia S.
Golodkov, Oleg N.
Novikova, Helen V.
Belov, Gennadii P.
Katsyuba, Sergey A.
Vandyukova, Elena E.
Lonnecke, Peter
Hey-Hawkins, Evamarie
Sinyashin, Oleg G.
机构：
[1] Russian Acad Sci, AE Arbuzov Organ & Phys Chem Inst, Kazan Sci Ctr, Kazan 420088, Russia
[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow, Russia
[3] Univ Leipzig, Inst Anorgan Chem, D-04103 Leipzig, Germany
来源：
HETEROATOM CHEMISTRY | 2006年 / 17卷 / 06期
关键词：
D O I：
10.1002/hc.20272
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Amphiphilic 1,5-diaza-3,7-diphosphacyclooctanes have been synthesized by condensation of hydrophobic primary arylphosphines, formaldehyde, and functionalized hydrophilic primary arylamines (5-aminoisophthalic acid and the sodium salt of sulfanilic acid). These compounds readily form P,P-chelate complexes with [PtCl2(cod)], which are stable in water. The catalytic activity of palladium catalysts with 1, 5-diaza-3,7-diphosphacyclooctane ligands was studied in the copolymerization of ethylene and carbon monoxide. (c) 2006 Wiley Periodicals, Inc.
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收藏
页码：499 / 513
页数：15
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