Luminescent complexes of 1,5-diaza-3,7-diphosphacyclooctanes with coinage metals

被引：4
|
作者：
Karasik, Andrey A. [1 ]
Strelnik, Igor D. [1 ]
Musina, Elvira I. [1 ]
Dayanova, Irina R. [1 ]
Elistratova, Julia G. [1 ]
Mustafina, Asiya R. [1 ]
Sinyashin, Oleg G. [1 ]
机构：
[1] RAS, FRC Kazan Sci Ctr, Arbuzov Inst Organ & Phys Chem, Kazan, Russia
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2019年 / 194卷 / 4-6期
关键词：
Aminomethylphosphines; cyclic diphosphines; stimuli-responsive luminescence; d(10)-complexes; PHOSPHINO AMINO-ACIDS; LIGANDS; CATALYSTS;
D O I：
10.1080/10426507.2018.1539854
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Cyclic aminomethylphosphines in general and 1,5-diaza-3,7-dihposphacyclooctanes in particular are widely used for the design of d(10)-metal complexes with catalytic or luminescent properties. 1,5-Diaza-3,7-diphosphacyclooctanes are chelating ligands towards Ni subgroup metals and chelating or bridging ligands towards copper subgroup metals. These ligands can be utilized for the design of polynuclear complexes with stimuli-responsive luminescence. Nowadays several complexes based on 1,5-diaza-3,7-diphosphacyclooctanes demonstrating stimuli-response of emission towards organic substrates or temperature are known. Some of the gold(I) complexes are able to sensitize the luminescent anionic rhenium cluster. Copper(I) complexes display rather strong luminescence with quantum yields 20-40%. [GRAPHICS] .
引用
收藏
页码：410 / 414
页数：5
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