A photoluminescent metal-organic framework with threefold interpenetrated diamond topological net

被引：6
|
作者：
Yang, E. [1 ,2 ]
Ding, Qingrong [1 ,2 ]
Kang, Yao [2 ]
Wang, Fei [2 ]
机构：
[1] Fujian Normal Univ, Coll Mat Sci & Engn, Fuzhou 350007, Fujian, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2014年 / 1072卷
基金：
中国国家自然科学基金;
关键词：
MOFs; Zinc; Interpenetration; Topology; Photoluminescence; Crystal structure; COORDINATION POLYMERS; HYDROGEN STORAGE; COMPLEXES; NETWORKS;
D O I：
10.1016/j.molstruc.2014.05.010
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new 3D metal-organic framework, [Zn3(IN)61.DMF.H20 (I, H-IN = isonicotinic acid), has been solvothermally synthesized and structurally characterized by single crystal X-ray diffraction. Structural analysis shows that compound I possesses a three-dimensional framework with 4-connected threefold interpenetrated diamond (dia) topological network where the Zn(ID centers are all 4-coordinated. Moreover, the photoluminescent property of this compound is investigated in the solid state at room temperature. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：228 / 231
页数：4
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