An eea Topological Metal-Organic Framework with High Methane Uptake

被引：3
|
作者：
Ji Qing-Yan [1 ]
Wang Qian [1 ]
Li Hong-Xin [1 ]
Xue Dong-Xu [1 ]
Bai Jun-Feng [1 ,2 ]
机构：
[1] Shaanxi Normal Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Appl Surface & Colloid Chem, Xian 710062, Shaanxi, Peoples R China
[2] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 33卷 / 11期
关键词：
Cu(II) complex; eea topology; CH4; storage; SELECTIVE CO2 CAPTURE; STORAGE; MOFS;
D O I：
10.11862/CJIC.2017.245
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new 3D porous MOF, {[CuL]center dot x(Solvent)}(n), (1) have been successfully synthesized based upon a bifunctional organic ligand with two carboxyl groups and one nitrogen donor of 5-(quinolin-6-yl)isophthalic acid (H2L). MOF 1 exhibits an eea topological network with the point (Schlafli) symbol of {4(2).6}(2){4(4).6(2).8(6).10(3)}. Remarkably, desolvated 1 performs a high CH4 adsorption enthalpy and high methane uptake at high pressure and 298 K. CCDC: 1559215, desolvated 1.
引用
收藏
页码：2031 / 2037
页数：7
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