Fabrication of Graphene Embedded LiFePO4 Using a Catalyst Assisted Self Assembly Method as a Cathode Material for High Power Lithium-Ion Batteries

被引:66
|
作者
Kim, WonKeun [1 ]
Ryu, WonHee [1 ]
Han, DongWook [1 ]
Lim, SungJin [1 ]
Eom, JiYong [2 ]
Kwon, HyukSang [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea
[2] Korea Automot Technol Inst, Automot Mat Convergence & Syst R&D Div, Clean & Energy Mat R&D Ctr, Cheonan Si 330912, Chungnam, South Korea
关键词
LiFePO4; graphene; catalyst assisted self assembly; cathode; lithium-ion battery; NANOSTRUCTURED LIFEPO4; PERFORMANCE; NANOMATERIALS; CAPACITY; STORAGE;
D O I
10.1021/am405335k
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We have designed a unique microstructure of graphene embedded LiFePO4 by a catalyst assisted self assembly method as a cathode material for high power lithium-ion batteries. The stable amide bonds between LiFePO4 and graphene were formed by the catalyst assisted self assembly. High conductive graphene provides a fast electron transfer path, and many pores inside the structure facilitate the lithium-ion diffusion. The graphene embedded LiFePO4 fabricated by the novel method shows enhanced cycling performance and rate-capability compared with that of carbon coated LiFePO4 as a cathode material for high power lithium-ion batteries.
引用
收藏
页码:4731 / 4736
页数:6
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