Fabrication of Graphene Embedded LiFePO4 Using a Catalyst Assisted Self Assembly Method as a Cathode Material for High Power Lithium-Ion Batteries

被引:66
|
作者
Kim, WonKeun [1 ]
Ryu, WonHee [1 ]
Han, DongWook [1 ]
Lim, SungJin [1 ]
Eom, JiYong [2 ]
Kwon, HyukSang [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea
[2] Korea Automot Technol Inst, Automot Mat Convergence & Syst R&D Div, Clean & Energy Mat R&D Ctr, Cheonan Si 330912, Chungnam, South Korea
关键词
LiFePO4; graphene; catalyst assisted self assembly; cathode; lithium-ion battery; NANOSTRUCTURED LIFEPO4; PERFORMANCE; NANOMATERIALS; CAPACITY; STORAGE;
D O I
10.1021/am405335k
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We have designed a unique microstructure of graphene embedded LiFePO4 by a catalyst assisted self assembly method as a cathode material for high power lithium-ion batteries. The stable amide bonds between LiFePO4 and graphene were formed by the catalyst assisted self assembly. High conductive graphene provides a fast electron transfer path, and many pores inside the structure facilitate the lithium-ion diffusion. The graphene embedded LiFePO4 fabricated by the novel method shows enhanced cycling performance and rate-capability compared with that of carbon coated LiFePO4 as a cathode material for high power lithium-ion batteries.
引用
收藏
页码:4731 / 4736
页数:6
相关论文
共 50 条
  • [21] Carbon Nanotubes as a Conductive Additive in LiFePO4 Cathode Material for Lithium-Ion Batteries
    Huang, Wenquan
    Cheng, Qing
    Qin, Xue
    RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2010, 46 (02) : 175 - 179
  • [22] Synthesis of Porous Structure LiFePO4/C as Cathode Material for Lithium-ion Batteries
    Liang Feng
    Dai Yong-Nian
    Yao Yao-Chun
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2010, 26 (09) : 1675 - 1679
  • [23] Carbon nanotubes as a conductive additive in LiFePO4 cathode material for lithium-ion batteries
    Wenquan Huang
    Qing Cheng
    Xue Qin
    Russian Journal of Electrochemistry, 2010, 46 : 175 - 179
  • [24] Physical and electrochemical properties of doped LiFePO4 as cathode material for lithium-ion batteries
    Yao, YX
    Duan, ZZ
    Li, YN
    Gu, HW
    Hua, ZQ
    Luan, WZ
    Wang, Y
    JOURNAL OF RARE EARTHS, 2004, 22 : 123 - 125
  • [25] Mechanism for Hydrothermal Synthesis of LiFePO4 Platelets as Cathode Material for Lithium-Ion Batteries
    Qin, Xue
    Wang, Xiaohui
    Xiang, Huimin
    Xie, Jie
    Li, Jingjing
    Zhou, Yanchun
    JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (39): : 16806 - 16812
  • [26] Fluorine doped carbon coating of LiFePO4 as a cathode material for lithium-ion batteries
    Wang, Xufeng
    Feng, Zhijun
    Hou, Xiaolong
    Liu, Lingling
    He, Min
    He, Xiaoshu
    Huang, Juntong
    Wen, Zhenhai
    CHEMICAL ENGINEERING JOURNAL, 2020, 379
  • [27] Review on Defects and Modification Methods of LiFePO4 Cathode Material for Lithium-Ion Batteries
    Chen, Shi-Peng
    Lv, Dan
    Chen, Jie
    Zhang, Yu-Hang
    Shi, Fa-Nian
    ENERGY & FUELS, 2022, 36 (03) : 1232 - 1251
  • [28] Theoretical investigation on niobium doped LiFePO4 cathode material for high performance lithium-ion batteries
    Karimzadeh, Sina
    Safaei, Babak
    Huang, Wei
    Jen, Tien-Chien
    JOURNAL OF ENERGY STORAGE, 2023, 67
  • [29] A novel LiFePO4/graphene/carbon composite as a performance-improved cathode material for lithium-ion batteries
    Su, Chang
    Bu, Xidan
    Xu, Lihuan
    Liu, Junlei
    Zhang, Cheng
    ELECTROCHIMICA ACTA, 2012, 64 : 190 - 195
  • [30] Characterization of LiFePO4 Cathode by Addition of Graphene for Lithium Ion Batteries
    Honggowiranto, Wagiyo
    Kartini, Evvy
    6TH NANOSCIENCE AND NANOTECHNOLOGY SYMPOSIUM (NNS2015), 2016, 1710