Macroscopic Supramolecular Assembly of Rigid Building Blocks Through a Flexible Spacing Coating

被引：106

作者：

Cheng, Mengjiao ^{[1
,2
]}

Shi, Feng ^{[1
,2
]}

Li, Jianshu ^{[3
]}

Lin, Zaifu ^{[3
]}

Jiang, Chao ^{[1
,2
]}

Xiao, Meng ^{[1
,2
]}

Zhang, Liqun ^{[1
,2
]}

Yang, Wantai ^{[1
,2
]}

Nishi, Toshio ^{[4
]}

机构：

[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China

[2] Beijing Univ Chem Technol, Key Lab Carbon Fiber & Funct Polymer, Minist Educ, Beijing 100029, Peoples R China

[3] Sichuan Univ, Coll Polymer Sci & Engn, Chengdu 610065, Peoples R China

[4] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Organ & Polymer Mat, Meguro Ku, Tokyo 1528552, Japan

来源：

ADVANCED MATERIALS | 2014年 / 26卷 / 19期

关键词：

supramolecular assembly; self-assembly; macroscopic supramolecular assembly; flexible spacing coating; multivalency; BETA-CYCLODEXTRIN; THERMODYNAMICS; DESIGN;

D O I：

10.1002/adma.201305177

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Macroscopic supramolecular assembly is a promising method for manufacturing macroscopic, ordered structures for tissue-engineering scaffolds. A flexible spacing coating is shown to overcome undesired surface and size effects and to enable assembly of macroscopic cubes with host/guest groups. The assembled pairs disassembled upon introduction of competitive guest molecules, thereby demonstrating a multivalent assembly mechanism. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3009 / 3013

页数：5

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