Macroscopic Supramolecular Assembly of Rigid Building Blocks Through a Flexible Spacing Coating

被引:106
|
作者
Cheng, Mengjiao [1 ,2 ]
Shi, Feng [1 ,2 ]
Li, Jianshu [3 ]
Lin, Zaifu [3 ]
Jiang, Chao [1 ,2 ]
Xiao, Meng [1 ,2 ]
Zhang, Liqun [1 ,2 ]
Yang, Wantai [1 ,2 ]
Nishi, Toshio [4 ]
机构
[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
[2] Beijing Univ Chem Technol, Key Lab Carbon Fiber & Funct Polymer, Minist Educ, Beijing 100029, Peoples R China
[3] Sichuan Univ, Coll Polymer Sci & Engn, Chengdu 610065, Peoples R China
[4] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Organ & Polymer Mat, Meguro Ku, Tokyo 1528552, Japan
关键词
supramolecular assembly; self-assembly; macroscopic supramolecular assembly; flexible spacing coating; multivalency; BETA-CYCLODEXTRIN; THERMODYNAMICS; DESIGN;
D O I
10.1002/adma.201305177
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Macroscopic supramolecular assembly is a promising method for manufacturing macroscopic, ordered structures for tissue-engineering scaffolds. A flexible spacing coating is shown to overcome undesired surface and size effects and to enable assembly of macroscopic cubes with host/guest groups. The assembled pairs disassembled upon introduction of competitive guest molecules, thereby demonstrating a multivalent assembly mechanism. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:3009 / 3013
页数:5
相关论文
共 50 条
  • [31] Borinic acid block copolymers: new building blocks for supramolecular assembly and sensory applications
    Cheng, Fei
    Wan, Wen-Ming
    Zhou, Yan
    Sun, Xiao-Li
    Bonder, Edward M.
    Jaekle, Frieder
    POLYMER CHEMISTRY, 2015, 6 (25) : 4650 - 4656
  • [32] Chiral Ruthenium(II) Complexes as Supramolecular Building Blocks for Heterometallic Self-Assembly
    Iranmanesh, Hasti
    Arachchige, Kasun S. A.
    Bhadbhade, Mohan
    Donald, William A.
    Liew, Jane Y.
    Liu, Kenny T. -C.
    Luis, Ena T.
    Moore, Evan G.
    Price, Jason R.
    Yan, Hong
    Yang, Jiajia
    Beves, Jonathon E.
    INORGANIC CHEMISTRY, 2016, 55 (24) : 12737 - 12751
  • [33] Molecular design of metal-ligand chromophoric building blocks and their supramolecular assembly and functions
    Yam, Vivian W. W.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [34] Double-Stranded Supramolecular Assembly through Salt Bridge Formation between Rigid and Flexible Amidine and Carboxylic Acid Strands
    Iida, Hiroki
    Shimoyama, Munenori
    Furusho, Yoshio
    Yashima, Eiji
    JOURNAL OF ORGANIC CHEMISTRY, 2010, 75 (02): : 417 - 423
  • [35] Oligo(phenyleneethynylene)s: Shape-Tunable Building Blocks for Supramolecular Self-Assembly
    Fernandez, Zulema
    Sanchez, Luis
    Santhosh Babu, Sukumaran
    Fernandez, Gustavo
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (18)
  • [36] Fluorescent supramolecular polymers:: Metal directed self-assembly of perylene bisimide building blocks
    Dobrawa, R
    Lysetska, M
    Ballester, P
    Grüne, M
    Würthner, F
    MACROMOLECULES, 2005, 38 (04) : 1315 - 1325
  • [37] Tuning the Amphiphilicity of Building Blocks: Controlled Self-Assembly and Disassembly for Functional Supramolecular Materials
    Wang, Yapei
    Xu, Huaping
    Zhang, Xi
    ADVANCED MATERIALS, 2009, 21 (28) : 2849 - 2864
  • [38] Chemical complexity-supramolecular self-assembly of synthetic and biological building blocks in water
    Zayed, Jameel M.
    Nouvel, Nicolas
    Rauwald, Urs
    Scherman, Oren A.
    CHEMICAL SOCIETY REVIEWS, 2010, 39 (08) : 2806 - 2816
  • [39] Stepwise Self-Assembly and Dynamic Exchange of Supramolecular Nanocages Based on Terpridine Building Blocks
    Zhang, Zhe
    Wang, Heng
    Shi, Junjuan
    Xu, Yaping
    Wang, Lei
    Shihadeh, Sammy
    Zhao, Fu-Jie
    Hao, Xin-Qi
    Wang, Pingshan
    Liu, Changlin
    Wang, Ming
    Li, Xiaopeng
    MACROMOLECULAR RAPID COMMUNICATIONS, 2018, 39 (22)
  • [40] The Assembly of Supramolecular Boxes and Coordination Polymers Based on Bis-Zinc-Salphen Building Blocks
    Kuil, Mark
    Puijk, Iris M.
    Kleij, Arian W.
    Tooke, Duncan M.
    Spek, Anthony L.
    Reek, Joost N. H.
    CHEMISTRY-AN ASIAN JOURNAL, 2009, 4 (01) : 50 - 57