Stereoselective cis glycosylation of 2-O-allyl protected glycosyl donors by intramolecular aglycon delivery (IAD)

被引：43
|
作者：
Seward, CMP
Cumpstey, I
Aloui, M
Ennis, SC
Redgrave, AJ
Fairbanks, AJ
机构：
[1] Univ Oxford, Dyson Perrins Lab, Oxford OX1 3QY, England
[2] Glaxo Wellcome Res & Dev Ltd, Med Res Ctr, Stevenage SG1 2NY, Herts, England
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 15期
关键词：
D O I：
10.1039/b004522p
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
2-O-Allyl protected glycosyl donors may be glycosylated stereoselectively via a three step sequence involving double bond isomerization, N-iodosuccinimide mediated tethering to a glycosyl acceptor and subsequent intramolecular glycosylation (intramolecular aglycon delivery, IAD).
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页码：1409 / 1410
页数：2
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