Stereoselective cis glycosylation of 2-O-allyl protected glycosyl donors by intramolecular aglycon delivery (IAD)

被引:43
|
作者
Seward, CMP
Cumpstey, I
Aloui, M
Ennis, SC
Redgrave, AJ
Fairbanks, AJ
机构
[1] Univ Oxford, Dyson Perrins Lab, Oxford OX1 3QY, England
[2] Glaxo Wellcome Res & Dev Ltd, Med Res Ctr, Stevenage SG1 2NY, Herts, England
关键词
D O I
10.1039/b004522p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
2-O-Allyl protected glycosyl donors may be glycosylated stereoselectively via a three step sequence involving double bond isomerization, N-iodosuccinimide mediated tethering to a glycosyl acceptor and subsequent intramolecular glycosylation (intramolecular aglycon delivery, IAD).
引用
收藏
页码:1409 / 1410
页数:2
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