The B1/2->X1/2 and C(2)1/2->A(2)1/2 transitions of ArKr+ produced from argon afterglow reactions of Kr

被引：7
|
作者：
Tsuji, M [1 ]
Tanaka, M [1 ]
Nishimura, Y [1 ]
机构：
[1] KYUSHU UNIV,GRAD SCH ENGN SCI,DEPT MOL SCI & TECHNOL,KASUGA,FUKUOKA 816,JAPAN
来源：
CHEMICAL PHYSICS LETTERS | 1997年 / 266卷 / 1-2期
关键词：
D O I：
10.1016/S0009-2614(96)01501-1
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two new visible emission systems of the ArKr+ heterodimer ion were observed in the 660-710 and 930-990 nm regions by the addition of Kr into an Ar afterglow. The former band was ascribed to the B 1/2 --> X 1/2 transition from the nu' = 0 and 1 levels, while the latter band was assigned to the C-2 1/2 --> A(2) 1/2 transition from the nu' similar or equal to 0-2 levels. The nu(0) value of the B 1/2 --> X 1/2 transition and the nu(c) value of the C-2 1/2 --> A(2) 1/2 transition were estimated to be 18103.4 +/- 2.3 and 10623.4 +/- 1.6 cm(-1), respectively. The Delta G(1/2) and D-0 values of the B 1/2 state and the omega(e), omega(e) x(e) and D-0 values of the A(2) 1/2 state were determined to be 44.7 +/- 0.7, 645, 93.7 +/- 1.2, 2.44 +/- 0.17 and 1093 cm(-1), respectively, on the basis of a vibrational analysis.
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页码：246 / 252
页数：7
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