Facile synthesis of well-defined sodium hydridoalkylzincates(II)

被引：21
|
作者：
Lennartson, Anders
Hakansson, Mikael [1 ]
Jagner, Susan
机构：
[1] Univ Gothenburg, Dept Chem, S-41296 Gothenburg, Sweden
[2] Chalmers, Dept Chem & Biol Engn, S-41296 Gothenburg, Sweden
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 35期
关键词：
anions; hydride ligands; sodium; synthetic methods; zinc;
D O I：
10.1002/anie.200701477
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) After you, Sir Edward: By following in the footsteps of Frankland and Wanklyn, it has been discovered that simple hydridoalkylzincates(II) (see picture) can be prepared in essentially quantitative yield from mixtures of sodium and an excess of neat dialkylzinc reagent, which also acts as solvent. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：6678 / 6680
页数：3
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