Facile synthesis of well-defined sodium hydridoalkylzincates(II)

被引：21
|
作者：
Lennartson, Anders
Hakansson, Mikael [1 ]
Jagner, Susan
机构：
[1] Univ Gothenburg, Dept Chem, S-41296 Gothenburg, Sweden
[2] Chalmers, Dept Chem & Biol Engn, S-41296 Gothenburg, Sweden
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 35期
关键词：
anions; hydride ligands; sodium; synthetic methods; zinc;
D O I：
10.1002/anie.200701477
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) After you, Sir Edward: By following in the footsteps of Frankland and Wanklyn, it has been discovered that simple hydridoalkylzincates(II) (see picture) can be prepared in essentially quantitative yield from mixtures of sodium and an excess of neat dialkylzinc reagent, which also acts as solvent. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：6678 / 6680
页数：3
相关论文
共 50 条
  • [21] Facile synthesis of well-defined cyclodextrin-pendant polymer via ATRP for nanostructure fabrication
    Zhang, Mingming
    Xiong, Qingqing
    Shen, Wei
    Zhang, Qiqing
    RSC ADVANCES, 2014, 4 (58): : 30566 - 30572
  • [22] Facile synthesis of well-defined CeO2 hollow spheres with a tunable pore structure
    Zhang, Jian
    Gong, Ming
    Tian, Chuanjin
    Wang, Chang-An
    CERAMICS INTERNATIONAL, 2016, 42 (05) : 6088 - 6093
  • [23] Facile and Green Synthesis of Well-Defined Nanocrystal Oxygen Evolution Catalysts by Rational Crystallization Regulation
    Jiang, Wulyu
    Xia, Lu
    Gomes, Bruna Ferreira
    Haumann, Michael
    Dau, Holger
    Roth, Christina
    Lehnert, Werner
    Shviro, Meital
    SMALL, 2024, 20 (21)
  • [24] Facile synthesis of uniform and well-defined single-crystal sodium tantalate cubes and their assembly into oriented two-dimensional nanofilm
    Gao, Rui
    Zhou, Shuxue
    Li, Wei
    Chen, Min
    Wu, Limin
    CRYSTENGCOMM, 2012, 14 (20) : 7031 - 7035
  • [25] SYNTHESIS OF WELL-DEFINED MACROMOLECULES BY CARBOCATIONIC TECHNIQUES
    KENNEDY, JP
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1985, 189 (APR-): : 10 - POLY
  • [26] Synthesis of well-defined dual functional siloxanes
    Sulaiman, Santy
    Goff, Jonathan
    Arkles, Barry
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
  • [27] A Facile Strategy for Preparation of α-Heterobifunctional Polystyrenes with Well-Defined Molecular Weight
    Wang, Yun
    Lu, Lu
    Wang, Hu
    Lu, Dairen
    Tao, Kang
    Bai, Ruke
    MACROMOLECULAR RAPID COMMUNICATIONS, 2009, 30 (22) : 1922 - 1927
  • [28] Intrachain radical chemistry as a facile route to well-defined polymeric nanostructures
    Berda, Erik
    Dickinson, Jessica
    Cole, Justin
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [29] Facile room temperature synthetic procedure for well-defined palladium nanocubes
    Bandyopadhyay, Susmita
    Obare, Sherine O.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 239
  • [30] Facile fabrication of well-defined hydrogel beads with magnetic nanocomposite shells
    Liu, Hongxia
    Wang, Chaoyang
    Gao, Quanxing
    Chen, Jianxin
    Ren, Biye
    Liu, Xinxing
    Tong, Zhen
    INTERNATIONAL JOURNAL OF PHARMACEUTICS, 2009, 376 (1-2) : 92 - 98
12345