Eosin Y Catalyzed Visible Light Oxidative C-C and C-P bond Formation

被引：544

作者：

Hari, Durga Prasad ^{[1
]}

Koenig, Burkhard ^{[1
]}

机构：

[1] Univ Regensburg, Inst Organ Chem, D-93053 Regensburg, Germany

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 15期

关键词：

PHOTOREDOX CATALYSIS; TERTIARY-AMINES; H BOND; ELECTROCHEMICAL OXIDATION; ORGANIC-SYNTHESIS; IMINIUM CATION; PET PROCESSES; ALDEHYDES; ORGANOCATALYSIS; PHOTOCATALYSIS;

D O I：

10.1021/ol201376v

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Eosin Y catalyzes efficiently the visible light mediated coupling of sp(3) C-H bonds adjacent to the nitrogen atom in tetrahydroisoquinoline derivatives in the absence of an external oxidant. Nitroalkanes, dialkyl malonates, malononitrile, and dialkyl phophonates were used as pronucleophiles in this metal-free, visible light oxidative coupling reaction.

引用

页码：3852 / 3855

页数：4

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