Eosin Y Catalyzed Visible Light Oxidative C-C and C-P bond Formation

被引：544
|
作者：
Hari, Durga Prasad [1 ]
Koenig, Burkhard [1 ]
机构：
[1] Univ Regensburg, Inst Organ Chem, D-93053 Regensburg, Germany
来源：
ORGANIC LETTERS | 2011年 / 13卷 / 15期
关键词：
PHOTOREDOX CATALYSIS; TERTIARY-AMINES; H BOND; ELECTROCHEMICAL OXIDATION; ORGANIC-SYNTHESIS; IMINIUM CATION; PET PROCESSES; ALDEHYDES; ORGANOCATALYSIS; PHOTOCATALYSIS;
D O I：
10.1021/ol201376v
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Eosin Y catalyzes efficiently the visible light mediated coupling of sp(3) C-H bonds adjacent to the nitrogen atom in tetrahydroisoquinoline derivatives in the absence of an external oxidant. Nitroalkanes, dialkyl malonates, malononitrile, and dialkyl phophonates were used as pronucleophiles in this metal-free, visible light oxidative coupling reaction.
引用
收藏
页码：3852 / 3855
页数：4
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