Transition metal complexes with (NO)3- anions

被引：7
|
作者：
Panas, I [1 ]
Snis, A [1 ]
Acke, F [1 ]
Johnson, T [1 ]
机构：
[1] Chalmers Univ Technol, Dept Inorgan Environm Chem, S-41296 Gothenburg, Sweden
来源：
CHEMICAL PHYSICS LETTERS | 1999年 / 302卷 / 5-6期
关键词：
D O I：
10.1016/S0009-2614(99)00197-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Density functional theory calculations are performed to determine structures, stabilities, and characteristic vibrational frequencies for metal complexes with nitric oxide trimer ligands. The study emphasizes the possible crucial importance of the 3.0 eV first ionization energy of the (NO)(3)(-) anion. Metal complexes with the composition M[(NO)(3)](2) are considered, where M is Mg, Ni, Cu, and Zn. Properties of the Cu(NO)(3) complex are evaluated for reference. Possible technological importance to catalysis and drug delivery systems is implied. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：431 / 436
页数：6
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