CHARACTERIZATIONS OF POLYPYRROLE-FILM-MODIFIED ELECTRODES INCORPORATED WITH ANIONS OF TRANSITION-METAL COMPLEXES

被引：2
|
作者：
Zhong Chuanjian [1 ]
Wang Shuiju
Wang Zhongquan
Tian Zhaowu
机构：
[1] Xiamen Univ, Dept Chem, Xiamen, Peoples R China
来源：
ACTA PHYSICO-CHIMICA SINICA | 1987年 / 3卷 / 06期
关键词：
D O I：
10.3866/PKU.WHXB19870608
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A procedure is described whereby Fe(CN)(6)(n-) (n = 3 or 4)-incorporated polypyrrole (PP) film can be formed on electrodes by electrochemical polymerization in aqueous solutions. Stable electrochemistry of the electrode thus formed in observed. The redox potential is affected by changes of the concentration of H+ in the electrolyted. By means of XPS, IR and ESR characterizations, the interactions between the incorporated species Fe(CN)(6)(n-) and PP+ has been investigated. A possible model of the orbital interactions involved in the film has been discussed.
引用
收藏
页码：599 / 603
页数：5
相关论文
共 10 条
  • [1] HIGHLY CONDUCTING POLYPARAPHENYLENE, POLYPYRROLE, AND POLYTHIOPHENE CHAINS - AN ABINITIO STUDY OF THE GEOMETRY AND ELECTRONIC-STRUCTURE MODIFICATIONS UPON DOPING
    BREDAS, JL
    THEMANS, B
    FRIPIAT, JG
    ANDRE, JM
    CHANCE, RR
    [J]. PHYSICAL REVIEW B, 1984, 29 (12): : 6761 - 6773
  • [2] BULL RA, 1984, J ELECTROCHEM SOC, V131, P688
  • [3] DIAZ DA, 1981, J ELEKTROLYTE CHEM, V128, P125
  • [4] SOLVENT EFFECTS ON REDOX POTENTIAL OF HEXACYANOFERRATE(III)-HEXACYANOFERRATE(II)
    GUTMANN, V
    GRITZNER, G
    DANKSAGMULLER, K
    [J]. INORGANICA CHIMICA ACTA, 1976, 17 (01) : 81 - 86
  • [5] THERMODYNAMIC ASPECTS OF POTASSIUM HEXACYANOFERRATE(3)-(2) SYSTEM .2. REDUCTION POTENTIAL
    HANANIA, GIH
    IRVINE, DH
    EATON, WA
    GEORGE, P
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1967, 71 (07): : 2022 - &
  • [6] MURRAY RW, 1984, ELECTROANAL CHEM, V13, P191
  • [7] CHEMICALLY MODIFIED ELECTRODES .20. RADIOFREQUENCY PLASMA POLYMERIZATION OF VINYLFERROCENE ON GLASSY-CARBON AND PLATINUM-ELECTRODES
    NOWAK, RJ
    SCHULTZ, FA
    UMANA, M
    LAM, R
    MURRAY, RW
    [J]. ANALYTICAL CHEMISTRY, 1980, 52 (02) : 315 - 321
  • [8] PFIUGER P, 1984, J CHEM PHYS, V80, P544
  • [9] 1985, IEPBC, pB13
  • [10] [No title captured]
1