A novel polyoxometalate tri-supported mixed-valent transition metal coordination complex

被引：12
|
作者：
Xiao, Li-Na
Wang, Yan
Chen, Yan
Peng, Yu
Li, Guo-Dong
Cui, Xiao-Bing [1 ]
Shi, Shu-Yun
Wang, Tie-Gang
Gao, Zhong-Min
Xu, Ji-Qing
机构：
[1] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 10期
关键词：
Polyoxometalates; Supported; Hydrothermal synthesis; Keggin; Hydrogen bonds; MOLYBDENUM-VANADIUM POLYOXOMETALATE; HYDROTHERMAL SYNTHESIS; DIRECTED SYNTHESIS; BUILDING-BLOCKS; POLYMER-CHAINS; DERIVATIVES; FRAMEWORKS; POLYANION;
D O I：
10.1016/j.inoche.2010.07.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new compound [Mo8V7O42][Cu(2,2'-bpy)(2)](2)[Cu(2,2'-bpy)]center dot 2H(3)O (1) has been synthesized under hydrothermal conditions and characterized by IR, UV-vis spectrum, elemental analysis, XRD, ESR, XPS, X-ray diffraction analysis and magnetic property study. Single-crystal X-ray structure analysis indicates that the compound 1 is a novel Keggin polyoxoanion tri-supported mixed-valent transition metal coordination complex. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：1217 / 1220
页数：4
相关论文
共 50 条
  • [31] Room-Temperature Characterization of a Mixed-Valent μ-Hydroxodicopper(II,III) Complex
    Isaac, James A.
    Gennarini, Federica
    Lopez, Isidoro
    Thibon-Pourret, Aurore
    David, Rolf
    Gellon, Gisele
    Gennaro, Beatrice
    Philouze, Christian
    Meyer, Franc
    Demeshko, Serhiy
    Le Mest, Yves
    Reglier, Marius
    Jamet, Helene
    Le Poul, Nicolas
    Belle, Catherine
    INORGANIC CHEMISTRY, 2016, 55 (17) : 8263 - 8266
  • [32] Isolation and characterization of a high-spin mixed-valent iron dinitrogen complex
    McWilliams, Sean F.
    Bunting, Philip C.
    Kathiresan, Venkatesan
    Mercado, Brandon Q.
    Hoffman, Brian M.
    Long, Jeffrey R.
    Holland, Patrick L.
    CHEMICAL COMMUNICATIONS, 2018, 54 (95) : 13339 - 13342
  • [33] PHOTOCHEMICAL REDUCTION OF WATER TO HYDROGEN CATALYZED BY MIXED-VALENT TETRANUCLEAR PLATINUM COMPLEX
    SAKAI, K
    MATSUMOTO, K
    JOURNAL OF COORDINATION CHEMISTRY, 1988, 18 (1-3) : 169 - 172
  • [34] High-spin wheel of a heptanuclear mixed-valent FeII,III complex
    Oshio, H
    Hoshino, N
    Ito, T
    Nakano, M
    Renz, F
    Gütlich, P
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (02) : 223 - +
  • [35] Preparation, Spectral and Thermal Characterization of Two Novel Mixed-Valent and Metal Trinuclear Oxo-centered Complexes
    Ghaemi, Arezoo
    Tavakkoli, Haman
    Khosravi, Iman
    ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (07) : 3177 - 3180
  • [36] ELECTROCHEMICAL STUDY OF RUTHENIUM(IV, III) DIMER CHLORIDE MIXED-VALENT COMPLEX
    EZERSKAYA, NA
    AFANASEVA, MV
    ZHURNAL NEORGANICHESKOI KHIMII, 1992, 37 (10): : 2223 - 2228
  • [37] Preparation, structure, and properties of a mixed-valent NiIINiIII amine-selenolate complex
    Kersting, B
    Siebert, D
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 1999, (01) : 189 - 193
  • [38] Highly efficient electrochemically driven water oxidation by graphenesupported mixed-valent Mn16-containing polyoxometalate
    Xiaolin Xing
    Meng Wang
    Rongji Liu
    Shuangshuang Zhang
    Ke Zhang
    Bin Li
    Guangjin Zhang
    GreenEnergy&Environment, 2016, 1 (02) : 138 - 143
  • [39] Linear, mixed-valent homocatenated tri-tin complexes featuring Sn-Sn bonds
    Chang, Wei-Chieh
    Raj, Ankit
    Hiramatsu, Hirotsugu
    Li, Han-Jung
    Ziegler, Micah S.
    Lin, Yichen
    Huang, Shengcih
    Liu, Hsueh-Ju
    CHEMICAL COMMUNICATIONS, 2020, 56 (50) : 6786 - 6789
  • [40] Fabrication of a novel mixed-valent copper-based coordination polymer as a fluorescent sensor for selective and efficient detection of multiple analytes
    Liu, Yu
    Yang, Wen
    Luan, Jian
    Zhang, Xiao-Sa
    Jian, Jun-Hong
    Liu, Hong-Xiao
    Li, Zheng-Kai
    Li, Wen-Ze
    INORGANIC CHEMISTRY COMMUNICATIONS, 2024, 170
12345