A novel polyoxometalate tri-supported mixed-valent transition metal coordination complex

被引：12
|
作者：
Xiao, Li-Na
Wang, Yan
Chen, Yan
Peng, Yu
Li, Guo-Dong
Cui, Xiao-Bing [1 ]
Shi, Shu-Yun
Wang, Tie-Gang
Gao, Zhong-Min
Xu, Ji-Qing
机构：
[1] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 10期
关键词：
Polyoxometalates; Supported; Hydrothermal synthesis; Keggin; Hydrogen bonds; MOLYBDENUM-VANADIUM POLYOXOMETALATE; HYDROTHERMAL SYNTHESIS; DIRECTED SYNTHESIS; BUILDING-BLOCKS; POLYMER-CHAINS; DERIVATIVES; FRAMEWORKS; POLYANION;
D O I：
10.1016/j.inoche.2010.07.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new compound [Mo8V7O42][Cu(2,2'-bpy)(2)](2)[Cu(2,2'-bpy)]center dot 2H(3)O (1) has been synthesized under hydrothermal conditions and characterized by IR, UV-vis spectrum, elemental analysis, XRD, ESR, XPS, X-ray diffraction analysis and magnetic property study. Single-crystal X-ray structure analysis indicates that the compound 1 is a novel Keggin polyoxoanion tri-supported mixed-valent transition metal coordination complex. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：1217 / 1220
页数：4
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