A novel polyoxometalate tri-supported mixed-valent transition metal coordination complex

被引：12
|
作者：
Xiao, Li-Na
Wang, Yan
Chen, Yan
Peng, Yu
Li, Guo-Dong
Cui, Xiao-Bing [1 ]
Shi, Shu-Yun
Wang, Tie-Gang
Gao, Zhong-Min
Xu, Ji-Qing
机构：
[1] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 10期
关键词：
Polyoxometalates; Supported; Hydrothermal synthesis; Keggin; Hydrogen bonds; MOLYBDENUM-VANADIUM POLYOXOMETALATE; HYDROTHERMAL SYNTHESIS; DIRECTED SYNTHESIS; BUILDING-BLOCKS; POLYMER-CHAINS; DERIVATIVES; FRAMEWORKS; POLYANION;
D O I：
10.1016/j.inoche.2010.07.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new compound [Mo8V7O42][Cu(2,2'-bpy)(2)](2)[Cu(2,2'-bpy)]center dot 2H(3)O (1) has been synthesized under hydrothermal conditions and characterized by IR, UV-vis spectrum, elemental analysis, XRD, ESR, XPS, X-ray diffraction analysis and magnetic property study. Single-crystal X-ray structure analysis indicates that the compound 1 is a novel Keggin polyoxoanion tri-supported mixed-valent transition metal coordination complex. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：1217 / 1220
页数：4
相关论文
共 50 条
  • [1] Polyoxometalate tri-supported transition metal complexes containing mixed-valent transition metal ions
    Fu, Li-Wei
    Xiao, Li-Na
    Guo, Hai-Yang
    Hu, Yang-Yang
    Guo, Lan-Lan
    Yu, Miao
    Cui, Xiao-Bing
    Xu, Ji-Qing
    JOURNAL OF COORDINATION CHEMISTRY, 2015, 68 (21) : 3814 - 3824
  • [2] One-pot Synthesis of Dihydropyrimidinones Using Polyoxometalate Tri-supported Transition Metal Complexes
    Fazaeli, Razieh
    Aliyan, Hamid
    Mohammadifar, Foroogh
    Zamani, Amir Abbas
    Bagi, Mohammad Javad
    JOURNAL OF THE KOREAN CHEMICAL SOCIETY-DAEHAN HWAHAK HOE JEE, 2011, 55 (04): : 666 - 672
  • [3] A MIXED-VALENT KEGGIN POLYOXOMETALATE INVOLVING MOLYBDENUM AND TUNGSTEN
    LECLAIRE, A
    BOREL, MM
    CHARDON, J
    RAVEAU, B
    MATERIALS RESEARCH BULLETIN, 1995, 30 (09) : 1075 - 1080
  • [4] Two new polyoxometalate tri-supported transition metal complexes constructed from bi-capped Keggin molybdenum-vanadium clusters and copper complex fragments
    Cui, Ji-Wen
    Cui, Xiao-Bing
    Xu, Jia-Ning
    Yu, Hai-Hui
    Xu, Ji-Qing
    Duan, Wei-Jie
    Wang, Tie-Gang
    JOURNAL OF MOLECULAR STRUCTURE, 2008, 891 (1-3) : 35 - 39
  • [5] Heterometallic mixed-valent molecular precursors for the synthesis of transition metal oxides
    Dikarev, Evgeny
    Lieberman, Craig
    Wei, Zheng
    Filatov, Alexander
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [6] A mixed-valent cyclodiphosphazane: Transition metal chemistry and cis/trans isomerisation
    GUDDEKOPPA S ANANTHNAG
    JOEL T MAGUE
    MARAVANJI S BALAKRISHNA
    Journal of Chemical Sciences, 2015, 127 : 979 - 986
  • [7] A mixed-valent cyclodiphosphazane: Transition metal chemistry and cis/trans isomerisation
    Ananthnag, Guddekoppa S.
    Mague, Joel T.
    Balakrishna, Maravanji S.
    JOURNAL OF CHEMICAL SCIENCES, 2015, 127 (06) : 979 - 986
  • [8] Attractive route to mixed-valent metal oxides
    Bernstein, S.N.
    Dunbar, K.R.
    Angewandte Chemie (International Edition in English), 1992, 31 (10):
  • [9] Colossal electroresistance response accompanied by metal-insulator transition in a mixed-valent vanadate
    Saha, Rafikul Ali
    Bandyopadhyay, Abhisek
    Schiesaro, Irene
    Bera, Arnab
    Mondal, Mintu
    Meneghini, Carlo
    Ray, Sugata
    PHYSICAL REVIEW B, 2021, 104 (04)
  • [10] Dinuclear complexes of di-, tri-, and mixed-valent samarium supported by the calix-tetrapyrrole ligand
    Dubé, T
    Gambarotta, S
    Yap, GPA
    ORGANOMETALLICS, 2000, 19 (05) : 817 - 823
12345