Diazidobis(5,5′-dimethyl-2,2′-bipyridyl-κ2 N,N′)cobalt(II) monohydrate

被引：3
|
作者：
Phatchimkun, Jaturong [1 ]
Chaichit, Narongsak [2 ]
机构：
[1] Vongchavalitkul Univ, Fac Engn, Dept Comp Sci, Nakhon Ratchasima 30000, Thailand
[2] Thammasat Univ, Fac Sci & Technol, Dept Phys, Rangsit 12121, Pathumthani, Thailand
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
D O I：
10.1107/S1600536811011305
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Co(C(12)H(12)N(2))(2)(N(3))(2)]center dot H(2)O, the Co(II) ion is situated on a crystallographic twofold axis and adopts a distorted octahedral geometry with the two dmbpy (dmbpy = 5,5'-dimethyl-2,2'-bipyridyl) and the two azido ligands in a cis arrangement. The solvent water molecule and one methyl group of the dmbpy ligand are disordered over two sets of sites in a 1:1 ratio. The crystal structure is stabilized by intramolecular C-H...N(dmbpy) and intermolecular O-H...N(azide) hydrogen bonds.
引用
收藏
页码：M516 / U1154
页数：11
相关论文
共 50 条
  • [31] Tris(2,2′-bipyridyl-κ2N,N′)nickel(II) β-octamolybdate tetrahydrate
    Su, Zhan-Hua
    Zhou, Bai-Bin
    Zhao, Zhi-Feng
    Zhang, Yu-Nan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M1206 - M1207
  • [32] (4,4'-DIMETHYL-2,2'-BIPYRIDYL-N,N')BIS(ISOCYANATO)PLATINUM(II)
    COYER, MJ
    HERBER, RH
    COHEN, S
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 : 1376 - 1378
  • [33] Bis[dichlorido(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)gold(III)] tetrachloridoaurate(III) dichloridooaurate(I)
    Karaca, Selvi
    Akkurt, Mehmet
    Safari, Nasser
    Amani, Vahid
    Buyukgungor, Orhan
    Abedi, Anita
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M335 - U940
  • [34] (2,2′-Bipyridyl-κ2N,N′)chlorido(DL-threoninato-κ2N,O1)copper(II) monohydrate
    Tan, Yi-Han
    Teoh, Siang-Guan
    Rosli, Mohd Mustaqim
    Fun, Hoong-Kun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M262 - U1638
  • [35] Electric dichroism studies on adsorption of Tris(5,5 prime -dimethyl-2,2 prime -bipyridyl)ruthenium(II) by a colloidally dispersed clay
    Yamagishi, A.
    Taniguchi, M.
    Takahashi, M.
    Asada, C.
    Matsushita, N.
    Sato, H.
    Journal of Physical Chemistry, 1994, 98 (31):
  • [36] EPR investigations of beta-deuteriated 5,5''-dimethyl-2,2':5',2''-terthiophenes
    Engelmann, G
    Stosser, R
    Kossmehl, G
    Jugelt, W
    Welzel, HP
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1996, (09): : 2015 - 2019
  • [37] Ethyl 5,5"-dimethyl-2,2′;6′,2"-terpyridine-4′-carboxylate
    Kickelbick, G
    Hoogenboom, R
    Schubert, US
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O4322 - O4324
  • [38] Trichlorido(5,5'-dimethyl-2,2'-bipyridine-kappa N-2,N')(dimethylformamide-kappa O)-indium(III) hemihydrate
    Shirvan, Sadif A.
    Dezfuli, Sara Haydari
    Khazali, Fereydoon
    Aghajeri, Manouchehr
    Borsalani, Ali
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1448 - +
  • [39] catena-Poly[[(5,5 '-dimethyl-2,2 '-bipyridine-kappa N-2,N ')cadmium]-di-mu-bromido]
    Shirvan, Sadif A.
    Dezfuli, Sara Haydari
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M846 - +
  • [40] Controlled polymerization of styrene using 5,5″-dimethyl-2,2′:6′,2″-terpyridine copper(II) complexes
    Schubert, Ulrich S.
    Spindler, Christian E.
    Eschbaumer, Christian
    Nuyken, Oskar
    American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, 1999, 40 (02): : 416 - 417
12345