Diazidobis(5,5′-dimethyl-2,2′-bipyridyl-κ2 N,N′)cobalt(II) monohydrate

被引：3
|
作者：
Phatchimkun, Jaturong [1 ]
Chaichit, Narongsak [2 ]
机构：
[1] Vongchavalitkul Univ, Fac Engn, Dept Comp Sci, Nakhon Ratchasima 30000, Thailand
[2] Thammasat Univ, Fac Sci & Technol, Dept Phys, Rangsit 12121, Pathumthani, Thailand
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
D O I：
10.1107/S1600536811011305
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Co(C(12)H(12)N(2))(2)(N(3))(2)]center dot H(2)O, the Co(II) ion is situated on a crystallographic twofold axis and adopts a distorted octahedral geometry with the two dmbpy (dmbpy = 5,5'-dimethyl-2,2'-bipyridyl) and the two azido ligands in a cis arrangement. The solvent water molecule and one methyl group of the dmbpy ligand are disordered over two sets of sites in a 1:1 ratio. The crystal structure is stabilized by intramolecular C-H...N(dmbpy) and intermolecular O-H...N(azide) hydrogen bonds.
引用
收藏
页码：M516 / U1154
页数：11
相关论文
共 50 条
  • [21] catena-Poly[[aqua(5,5'-dimethyl-2,2'-bipyridine-κ2 N,N')copper(II)]-μ-2,2'-oxydibenzoato-κ2 O:O']
    Mei, Chong-Zhen
    Xiong, Han-Lin
    Zhang, Peng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M905 - U446
  • [22] The Ovicidal, Larvacidal and Adulticidal Properties of 5,5′-Dimethyl-2,2′-Bipyridyl against Drosophila melanogaster
    Van Hiel, Matthias B.
    Breugelmans, Bert
    Pagel, Charles N.
    Williams, Adam K.
    Varan, Aiden K.
    Burke, Richard
    Bowles, Vernon M.
    Batterham, Philip
    PLOS ONE, 2012, 7 (11):
  • [23] Trichlorido(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)(methanol-κO)indium(III)
    Kalateh, Khadijeh
    Ahmadi, Roya
    Ebadi, Amin
    Amani, Vahid
    Khavasi, Hamid Reza
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1353 - U75
  • [24] ELECTRIC DICHROISM STUDIES ON ADSORPTION OF TRIS(5,5'-DIMETHYL-2,2'-BIPYRIDYL)RUTHENIUM(II) BY A COLLOIDALLY DISPERSED CLAY
    YAMAGISHI, A
    TANIGUCHI, M
    TAKAHASHI, M
    ASADA, C
    MATSUSHITA, N
    SATO, H
    JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (31): : 7555 - 7561
  • [25] catena-Poly[[dicyanamido(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)copper(II)]-μ-dicyanamido-κ2N1:N5]
    Kooijman, H
    Spek, AL
    van Albada, GA
    Reedijk, J
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2002, 58 : m124 - m126
  • [26] Tris(2,2′-bipyridyl-κ2N,N′)copper(II) hexafluoridophosphate
    Wang, Li
    Yang, Xue-Yun
    Huang, Wei
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : m835 - m836
  • [27] Symmetrical and unsymmetrical derivatives of 5,5′-dimethyl-2,2′-bipyridine
    Al-Sayah, MH
    Salameh, AS
    ARABIAN JOURNAL FOR SCIENCE AND ENGINEERING, 2000, 25 (2A): : 67 - 72
  • [28] Bis[tris(2,2′-bipyridyl-κ2N,N′)cobalt(II)] cyclo-tetravanadate undecahydrate
    Zhang, Ke
    Liang, Da-Dong
    Wang, Ming-Hui
    Liu, Yan
    Luan, Guo-You
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2013, 69 : 138 - +
  • [29] Synthesis, crystal structure and magnetic properties of (acetato-κ2O,O′)bis(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)nickel(II) perchlorate monohydrate
    Farkasova, Nela
    Cernak, Juraj
    Falvello, Larry R.
    Orendac, Martin
    Boca, Roman
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2015, 71 : 252 - +
  • [30] A novel one-dimensional metal-organic framework with a μ-cyanido-argentate group: catena-poly[[(5,5′-dimethyl-2,2′-bipyridyl-κ2N,N′)silver(I)]-μ-cyanido-κ2N:C]
    Piromchom, Jureepan
    Othong, Jintana
    Boonmak, Jaursup
    Mutikainen, Ilpo
    Youngme, Sujittra
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2015, 71 : 1057 - +
12345