Diazidobis(5,5′-dimethyl-2,2′-bipyridyl-κ2 N,N′)cobalt(II) monohydrate

被引：3
|
作者：
Phatchimkun, Jaturong [1 ]
Chaichit, Narongsak [2 ]
机构：
[1] Vongchavalitkul Univ, Fac Engn, Dept Comp Sci, Nakhon Ratchasima 30000, Thailand
[2] Thammasat Univ, Fac Sci & Technol, Dept Phys, Rangsit 12121, Pathumthani, Thailand
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
D O I：
10.1107/S1600536811011305
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Co(C(12)H(12)N(2))(2)(N(3))(2)]center dot H(2)O, the Co(II) ion is situated on a crystallographic twofold axis and adopts a distorted octahedral geometry with the two dmbpy (dmbpy = 5,5'-dimethyl-2,2'-bipyridyl) and the two azido ligands in a cis arrangement. The solvent water molecule and one methyl group of the dmbpy ligand are disordered over two sets of sites in a 1:1 ratio. The crystal structure is stabilized by intramolecular C-H...N(dmbpy) and intermolecular O-H...N(azide) hydrogen bonds.
引用
收藏
页码：M516 / U1154
页数：11
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