Reactions of anodic and chemical aromatic substitution

被引：24
|
作者：
Petrosyan, Vladimir A. [1 ]
机构：
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2011年 / 21卷 / 03期
关键词：
ELECTROCHEMICAL OXIDATION; CATION RADICALS; EE SYSTEMS; 1,4-DIMETHOXYBENZENE; ELECTROSYNTHESIS; ACETOXYLATION; MECHANISM; HYDROGEN; N-(2,5-DIMETHOXYPHENYL)AZOLES; 9,10-DIPHENYLANTHRACENE;
D O I：
10.1016/j.mencom.2011.04.001
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Among anodic (electro-oxidative) aromatic substitution reactions there is a specific group of reactions involving direct nucleophilic replacement of hydrogen atom at the aromatic ring, or S-N(H)(An) reactions. These reactions occurring via an intermediate sigma(+) complex represent a versatile type (the hydrogen atom that is easily removed as a proton) of S-N(H) reactions, on the one hand, and are somewhat similar to aromatic electrophilic substitutions, on the other hand.
引用
收藏
页码：115 / 121
页数：7
相关论文
共 50 条
12345