Reactions of anodic and chemical aromatic substitution

被引：24

作者：

Petrosyan, Vladimir A. ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2011年 / 21卷 / 03期

关键词：

ELECTROCHEMICAL OXIDATION; CATION RADICALS; EE SYSTEMS; 1,4-DIMETHOXYBENZENE; ELECTROSYNTHESIS; ACETOXYLATION; MECHANISM; HYDROGEN; N-(2,5-DIMETHOXYPHENYL)AZOLES; 9,10-DIPHENYLANTHRACENE;

D O I：

10.1016/j.mencom.2011.04.001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Among anodic (electro-oxidative) aromatic substitution reactions there is a specific group of reactions involving direct nucleophilic replacement of hydrogen atom at the aromatic ring, or S-N(H)(An) reactions. These reactions occurring via an intermediate sigma(+) complex represent a versatile type (the hydrogen atom that is easily removed as a proton) of S-N(H) reactions, on the one hand, and are somewhat similar to aromatic electrophilic substitutions, on the other hand.

引用

页码：115 / 121

页数：7

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