Mononuclear Cobalt and Iron o-Quinone Complexes with Tetradentate N-Donor Bases: Structures and Properties

被引：17
|
作者：
Starikova, A. A. [1 ]
Chegerev, M. G. [1 ]
Starikov, A. G. [1 ]
机构：
[1] Southern Fed Univ, Inst Phys & Organ Chem, Rostov Na Donu, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2020年 / 46卷 / 03期
基金：
俄罗斯科学基金会;
关键词：
iron; cobalt; o-benzoquinone; tetraazamacrocyclic ligands; magnetic properties; electronic structure; VALENCE-TAUTOMERIC INTERCONVERSION; TRANSITION-METAL-COMPLEXES; INTRAMOLECULAR ELECTRON-TRANSFER; CLEAVING CATECHOL DIOXYGENASES; REDOX-ACTIVE LIGANDS; SPIN-CROSSOVER; MAGNETIC-PROPERTIES; CHARGE-DISTRIBUTION; TRIPODAL LIGANDS; DIOXOLENE COMPLEXES;
D O I：
10.1134/S1070328420030070
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Published data on the electronic structures and magnetic behavior of the mononuclear cobalt and iron o-benzoquinone complexes with tetradentate nitrogen-containing bases are reviewed. The chosen objects are of significant interest due to their ability to manifest magnetic bistability, indicating wide prospects of the practical use of compounds of this class in molecular electronics and spintronics. The influence of structural features of the complexes on their magnetic properties is discussed on the basis of the quantum-chemical calculation results.
引用
收藏
页码：193 / 213
页数：21
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