Mononuclear Cobalt and Iron o-Quinone Complexes with Tetradentate N-Donor Bases: Structures and Properties

被引：17
|
作者：
Starikova, A. A. [1 ]
Chegerev, M. G. [1 ]
Starikov, A. G. [1 ]
机构：
[1] Southern Fed Univ, Inst Phys & Organ Chem, Rostov Na Donu, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2020年 / 46卷 / 03期
基金：
俄罗斯科学基金会;
关键词：
iron; cobalt; o-benzoquinone; tetraazamacrocyclic ligands; magnetic properties; electronic structure; VALENCE-TAUTOMERIC INTERCONVERSION; TRANSITION-METAL-COMPLEXES; INTRAMOLECULAR ELECTRON-TRANSFER; CLEAVING CATECHOL DIOXYGENASES; REDOX-ACTIVE LIGANDS; SPIN-CROSSOVER; MAGNETIC-PROPERTIES; CHARGE-DISTRIBUTION; TRIPODAL LIGANDS; DIOXOLENE COMPLEXES;
D O I：
10.1134/S1070328420030070
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Published data on the electronic structures and magnetic behavior of the mononuclear cobalt and iron o-benzoquinone complexes with tetradentate nitrogen-containing bases are reviewed. The chosen objects are of significant interest due to their ability to manifest magnetic bistability, indicating wide prospects of the practical use of compounds of this class in molecular electronics and spintronics. The influence of structural features of the complexes on their magnetic properties is discussed on the basis of the quantum-chemical calculation results.
引用
收藏
页码：193 / 213
页数：21
相关论文
共 50 条
  • [31] Molecular and electronic structures of paramagnetic gallium complexes with differently charged o-quinone ligands
    A. V. Maleeva
    O. Yu. Trofimova
    I. V. Ershova
    K. V. Arsenyeva
    K. I. Pashanova
    I. A. Yakushev
    A. V. Cherkasov
    R. R. Aysin
    A. V. Piskunov
    Russian Chemical Bulletin, 2022, 71 : 1441 - 1452
  • [32] LIPOPHILIC TECHNETIUM COMPLEXES - TECHNETIUM CHELATES OF SOME O-DONOR, N-DONOR, S-DONOR SCHIFF-BASES
    SPIES, H
    PIETZSCH, HJ
    ABRAM, U
    JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 1984, 85 (06) : 339 - 344
  • [33] Molecular and electronic structures of paramagnetic gallium complexes with differently charged o-quinone ligands
    Maleeva, A., V
    Trofimova, O. Yu
    Ershova, I., V
    Arsenyeva, K., V
    Pashanova, K., I
    Yakushev, I. A.
    Cherkasov, A., V
    Aysin, R. R.
    Piskunov, A., V
    RUSSIAN CHEMICAL BULLETIN, 2022, 71 (07) : 1441 - 1452
  • [34] Cyclometalated Iron and Ruthenium Complexes Supported by a Tetradentate Ligand Scaffold with Mixed O, N, and C Donor Atoms: Synthesis, Structures, and Excited-State Properties
    Law, Kwok-Chung
    Tang, Zhou
    Wu, Liangliang
    Wan, Qingyun
    To, Wai-Pong
    Chang, Xiaoyong
    Low, Kam-Hung
    Liu, Yungen
    Che, Chi-Ming
    ORGANOMETALLICS, 2022, 41 (04) : 418 - 429
  • [35] Syntheses, structures, and properties of two luminous mercury(II) halide compounds containing a tetradentate N-donor Schiff base
    Satapathi, Smita
    Chattopadhyay, Soumi
    Roy, Subhasis
    Bhar, Kishalay
    Mitra, Partha
    Ghosh, Barindra Kumar
    JOURNAL OF MOLECULAR STRUCTURE, 2012, 1030 : 138 - 144
  • [36] Solution and solid state structures of uranium(III) and lanthanum(III) iodide complexes of tetradentate tripodal neutral N-donor ligands
    Wietzke, R
    Mazzanti, M
    Latour, JM
    Pécaut, J
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (22): : 4167 - 4173
  • [37] Ruthenium Complexes of Rigid, Dianionic, Tetradentate N-Donor Ligands and their Potential as Catalysts for Water Oxidation
    Rajabi, Sheida
    Ruettger, Franziska
    Luecken, Jana
    Dechert, Sebastian
    John, Michael
    Meyer, Franc
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2023, 26 (03)
  • [38] DIOXOURANIUM(VI) COMPLEXES WITH SOME N-DONOR AND O-DONOR LIGANDS
    SINGH, B
    SINGH, RN
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1987, 26 (08): : 702 - 704
  • [39] Synthesis and spectral properties of cobalt(III) complexes containing SCN dimethylglyoxime and heterocyclic N-donor ligands
    Nayak, SC
    Sahoo, KK
    Das, PK
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2003, 42 (03): : 537 - 539
  • [40] Syntheses, structures, and optical properties of novel zinc(II) complexes with multicarboxylate and N-donor ligands
    Chu, Qian
    Liu, Guang-Xiang
    Huang, Yong-Qing
    Wang, Xiao-Feng
    Sun, Wei-Yin
    DALTON TRANSACTIONS, 2007, (38) : 4302 - 4311
12345