Mononuclear Cobalt and Iron o-Quinone Complexes with Tetradentate N-Donor Bases: Structures and Properties

被引：17
|
作者：
Starikova, A. A. [1 ]
Chegerev, M. G. [1 ]
Starikov, A. G. [1 ]
机构：
[1] Southern Fed Univ, Inst Phys & Organ Chem, Rostov Na Donu, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2020年 / 46卷 / 03期
基金：
俄罗斯科学基金会;
关键词：
iron; cobalt; o-benzoquinone; tetraazamacrocyclic ligands; magnetic properties; electronic structure; VALENCE-TAUTOMERIC INTERCONVERSION; TRANSITION-METAL-COMPLEXES; INTRAMOLECULAR ELECTRON-TRANSFER; CLEAVING CATECHOL DIOXYGENASES; REDOX-ACTIVE LIGANDS; SPIN-CROSSOVER; MAGNETIC-PROPERTIES; CHARGE-DISTRIBUTION; TRIPODAL LIGANDS; DIOXOLENE COMPLEXES;
D O I：
10.1134/S1070328420030070
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Published data on the electronic structures and magnetic behavior of the mononuclear cobalt and iron o-benzoquinone complexes with tetradentate nitrogen-containing bases are reviewed. The chosen objects are of significant interest due to their ability to manifest magnetic bistability, indicating wide prospects of the practical use of compounds of this class in molecular electronics and spintronics. The influence of structural features of the complexes on their magnetic properties is discussed on the basis of the quantum-chemical calculation results.
引用
收藏
页码：193 / 213
页数：21
相关论文
共 50 条
  • [1] Mononuclear Cobalt and Iron o-Quinone Complexes with Tetradentate N-Donor Bases: Structures and Properties
    A. A. Starikova
    M. G. Chegerev
    A. G. Starikov
    Russian Journal of Coordination Chemistry, 2020, 46 : 193 - 213
  • [2] Syntheses, structures and molecular properties of two mononuclear cobalt(III) halide complexes containing a tetradentate N-donor Schiff base
    Khan, Sumitava
    Bhar, Kishalay
    Roy, Subhasis
    Ramachandran, Krishnakumar
    Ghosh, Barindra Kumar
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2011, 50 (9-10): : 1429 - 1435
  • [3] Syntheses, structures, and properties of two mononuclear cobalt(III) azido complexes containing a tetradentate N-donor Schiff base as end-capping ligand
    Sumitava Khan
    Subhasis Roy
    Kishalay Bhar
    Partha Mitra
    Alexandra M. Z. Slawin
    Barindra Kumar Ghosh
    Transition Metal Chemistry, 2011, 36 : 99 - 106
  • [4] Syntheses, structures, and properties of two mononuclear cobalt(III) azido complexes containing a tetradentate N-donor Schiff base as end-capping ligand
    Khan, Sumitava
    Roy, Subhasis
    Bhar, Kishalay
    Mitra, Partha
    Slawin, Alexandra M. Z.
    Ghosh, Barindra Kumar
    TRANSITION METAL CHEMISTRY, 2011, 36 (01) : 99 - 106
  • [5] Magnetically bistable cobalt-dioxolene complexes with a tetradentate N-donor base
    Chegerev, Maxim G.
    Korchagin, Denis, V
    Shilov, Gennady, V
    Efimov, Nikolay N.
    Starikov, Andrey G.
    Piskunov, Alexandr, V
    Chernyshev, Anatoly, V
    Bulgakov, Aleksei N.
    Minkin, Vladimir, I
    Palii, Andrei, V
    Aldoshin, Sergey M.
    DALTON TRANSACTIONS, 2022, 51 (44) : 16876 - 16889
  • [6] Binuclear bis(o-semiquinonato)cobalt(II) complexes with bridging tetradentate N-donor ligand
    Zolotukhin, Alexey A.
    Bubnov, Michael P.
    Bogomyakov, Artem S.
    Protasenko, Natalia A.
    Fukin, Georgy K.
    Grishin, Ivan D.
    Cherkasov, Vladimir K.
    INORGANICA CHIMICA ACTA, 2016, 440 : 16 - 20
  • [7] N-donor ligand complexes of nickel, zinc and copper: Comparisons with tetradentate N-donor ligands derived from Schiff bases
    Mustapha, Abdullahi
    Duckmanton, Paul
    Reglinski, John
    Kennedy, Alan R.
    POLYHEDRON, 2010, 29 (13) : 2590 - 2594
  • [8] Syntheses, structures, and luminescence behavior of terephthalate bridged lead(II) complexes with tetradentate N-donor Schiff bases
    Roy, Subhasis
    Choubey, Somnath
    Bhar, Kishalay
    Khan, Sumitava
    Mitra, Partha
    Ghosh, Barindra Kumar
    JOURNAL OF MOLECULAR STRUCTURE, 2013, 1051 : 328 - 335
  • [9] Synthesis, structure and properties of mononuclear cobalt(II) and cobalt(III) pseudohalide complexes containing N-donor Schiff bases: Synthetic control of metal oxidation levels
    Rahaman, SH
    Chowdhury, H
    Bose, D
    Ghosh, R
    Hung, CH
    Ghosh, BK
    POLYHEDRON, 2005, 24 (13) : 1755 - 1763
  • [10] Synthesis, Crystal Structures and Luminescent Properties of Two Nickel Mononuclear Complexes Containing N-donor Ligands
    Guan Lei
    Gao Wei
    Zhang Zu-Kang
    Wang Ying
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2014, 30 (05) : 1187 - 1194
12345