Immobilization of a molecular cobalt cubane catalyst on porous BiVO4via electrochemical polymerization for efficient and stable photoelectrochemical water oxidation

被引：20

作者：

Jiang, Wenchao ^{[1
]}

Yang, Xiaoxuan ^{[1
]}

Li, Fei ^{[2
]}

Zhang, Qian ^{[1
]}

Li, Siyuan ^{[1
]}

Tong, Haili ^{[1
]}

Jiang, Yi ^{[1
]}

Xia, Lixin ^{[1
]}

机构：

[1] Liaoning Univ, Coll Chem, Shenyang 110036, Liaoning, Peoples R China

[2] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Liaoning, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 10期

基金：

中国国家自然科学基金;

关键词：

ARTIFICIAL PHOTOSYNTHESIS; METAL; PHOTOANODES;

D O I：

10.1039/c8cc08802k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile and efficient strategy is described in this communication for preparing a molecular catalyst/semiconductor hybrid photoanode by immobilizing a cobalt cubane water oxidation catalyst onto a porous BiVO4 electrode via electrochemical polymerization. With the introduction of Vpa as the anchoring linkage, the poly-1/Vpa/Al2O3/BiVO4 photoanode exhibits high performance as well as stability for photoelectrochemical water oxidation.

引用

页码：1414 / 1417

页数：4

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