Immobilization of a molecular cobalt cubane catalyst on porous BiVO4via electrochemical polymerization for efficient and stable photoelectrochemical water oxidation

被引：20
|
作者：
Jiang, Wenchao [1 ]
Yang, Xiaoxuan [1 ]
Li, Fei [2 ]
Zhang, Qian [1 ]
Li, Siyuan [1 ]
Tong, Haili [1 ]
Jiang, Yi [1 ]
Xia, Lixin [1 ]
机构：
[1] Liaoning Univ, Coll Chem, Shenyang 110036, Liaoning, Peoples R China
[2] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Liaoning, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 10期
基金：
中国国家自然科学基金;
关键词：
ARTIFICIAL PHOTOSYNTHESIS; METAL; PHOTOANODES;
D O I：
10.1039/c8cc08802k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A facile and efficient strategy is described in this communication for preparing a molecular catalyst/semiconductor hybrid photoanode by immobilizing a cobalt cubane water oxidation catalyst onto a porous BiVO4 electrode via electrochemical polymerization. With the introduction of Vpa as the anchoring linkage, the poly-1/Vpa/Al2O3/BiVO4 photoanode exhibits high performance as well as stability for photoelectrochemical water oxidation.
引用
收藏
页码：1414 / 1417
页数：4
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