Catalytic Asymmetric Inverse-Electron-Demand Hetero-Diels-Alder Reactions

被引：80
|
作者：
Xie, Mingsheng [1 ]
Lin, Lili [1 ]
Feng, Xiaoming [1 ]
机构：
[1] Sichuan Univ, Coll Chem, Key Lab Green Chem & Technol, Minist Educ, Chengdu 610064, Peoples R China
来源：
CHEMICAL RECORD | 2017年 / 17卷 / 12期
基金：
中国国家自然科学基金;
关键词：
asymmetric synthesis; hetero-Diels-Alder reaction; inverse-electron-demand cycloaddition; heterocycles; BETA; GAMMA-UNSATURATED ALPHA-KETOESTERS; HIGHLY ENANTIOSELECTIVE SYNTHESIS; BIFUNCTIONAL ORGANOCATALYTIC STRATEGY; DIHYDROPYRAN-FUSED INDOLES; ORTHO-QUINONE METHIDES; BINARY-ACID CATALYSIS; ONE-STEP SYNTHESIS; 4+2 CYCLOADDITION; POVAROV REACTION; LEWIS-ACID;
D O I：
10.1002/tcr.201700006
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this review, the recent developments in catalytic asymmetric inverse-electron-demand hetero-Diels-Alder reaction, which is recognized as one of the most powerful routes to construct highly functionalized and enantioenriched six-membered heterocycles, are described. The article is organized on the basis of different kinds of electron-deficient heterodienes, including ,-unsaturated ketones/aldehydes, o-benzoquinones, ,-unsaturated imines, N-aryl imines, o-benzoqinone imides, and other aza-olefins.
引用
收藏
页码：1184 / 1202
页数：19
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