Catalytic Asymmetric Inverse-Electron-Demand Hetero-Diels-Alder Reactions

被引：80

作者：

Xie, Mingsheng ^{[1
]}

Lin, Lili ^{[1
]}

Feng, Xiaoming ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Key Lab Green Chem & Technol, Minist Educ, Chengdu 610064, Peoples R China

来源：

CHEMICAL RECORD | 2017年 / 17卷 / 12期

基金：

中国国家自然科学基金;

关键词：

asymmetric synthesis; hetero-Diels-Alder reaction; inverse-electron-demand cycloaddition; heterocycles; BETA; GAMMA-UNSATURATED ALPHA-KETOESTERS; HIGHLY ENANTIOSELECTIVE SYNTHESIS; BIFUNCTIONAL ORGANOCATALYTIC STRATEGY; DIHYDROPYRAN-FUSED INDOLES; ORTHO-QUINONE METHIDES; BINARY-ACID CATALYSIS; ONE-STEP SYNTHESIS; 4+2 CYCLOADDITION; POVAROV REACTION; LEWIS-ACID;

D O I：

10.1002/tcr.201700006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this review, the recent developments in catalytic asymmetric inverse-electron-demand hetero-Diels-Alder reaction, which is recognized as one of the most powerful routes to construct highly functionalized and enantioenriched six-membered heterocycles, are described. The article is organized on the basis of different kinds of electron-deficient heterodienes, including ,-unsaturated ketones/aldehydes, o-benzoquinones, ,-unsaturated imines, N-aryl imines, o-benzoqinone imides, and other aza-olefins.

引用

页码：1184 / 1202

页数：19

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