Synthesis and characterization of 2-dimethylaminoethyl thiolate complexes of palladium(II) and platinum(II)

被引：0
|
作者：
Dey, S
Jain, VK [1 ]
Knoedler, A
Kaim, W
机构：
[1] Bhabha Atom Res Ctr, Novel Mat & Struct Chem Div, Bombay 400085, Maharashtra, India
[2] Univ Stuttgart, Inst Anorgan Chem, D-70569 Stuttgart, Germany
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2003年 / 42卷 / 09期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of Na2PdCl4 with Me2NCH2CH2SH.HCl in methanol affords a trimeric complex [PdCl(SCH2CH2NMe2)](3). Treatment of [M2Cl2(mu-Cl)(2)(PR3)(2)] (M = Pd or Pt) with Me2NCH2CH2SH.HCl in the presence of NaHCO3 Yields complexes of the type [MCl(SCH2CH2NMe2)(PR3)](n) (n = 1 or 2). These complexes have been isolated as monomeric species containing chelating thiolate ligands. In some cases, with more basic phosphines, binuclear complexes (n = 2) containing bridging thiolate ligands are also formed. All complexes have been characterized by elemental analysis and NMR spectroscopy. The structure of [PdCl(SCH2CH2NMe2)(PPh3)] (2c) has been established by X-ray crystallography.
引用
收藏
页码：2339 / 2343
页数：5
相关论文
共 50 条
  • [31] The synthesis and mesomorphism of some acetylide complexes of platinum(II) and palladium(II)
    Bruce, DW
    Lea, MS
    Marsden, JR
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1996, 275 : 183 - 194
  • [32] Reactions of palladium(II) and platinum(II) bis(azido) complexes with isocyanides: synthesis and structural characterization of palladium(II) and platinum(II) complexes containing carbodiimido (or bis( carbodiimido)) and bis(tetrazolato) ligands
    Kim, YJ
    Kwak, YS
    Joo, YS
    Lee, SW
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (02): : 144 - 151
  • [33] Synthesis, experimental and theoretical characterization of palladium(II) and platinum(II) saccharinate complexes with 2-(2-pyridyl)benzimidazole
    Guney, Emel
    Kaya, Yunus
    Yilmaz, Veysel T.
    Gumus, Sedat
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2011, 79 (05) : 1171 - 1178
  • [34] Copper(II), palladium(II) and platinum(II) chloride complexes with 5-amino-2-tert-butyltetrazole: Synthesis, characterization and cytotoxicity
    Voitekhovich, Sergei V.
    Serebryanskaya, Tadyana V.
    Lyakhov, Alexander S.
    Gaponik, Pavel N.
    Ivashkevich, Oleg A.
    POLYHEDRON, 2009, 28 (16) : 3614 - 3620
  • [35] Palladium(II) and platinum(II) complexes with arylthioethenes
    AlAllaf, TAK
    Buttrus, NH
    Hitchcock, PB
    ASIAN JOURNAL OF CHEMISTRY, 1997, 9 (02) : 187 - 194
  • [36] ALKOXALYL COMPLEXES OF PALLADIUM(II) AND PLATINUM(II)
    DOBRZYNSKI, ED
    ANGELICI, RJ
    INORGANIC CHEMISTRY, 1975, 14 (01) : 59 - 63
  • [37] Platinum(II) and palladium(II) saccharinate complexes
    Henderson, W
    Nicholson, BK
    McCaffrey, LJ
    INORGANICA CHIMICA ACTA, 1999, 285 (01) : 145 - 148
  • [38] HYDROXY COMPLEXES OF PLATINUM(II) AND PALLADIUM(II)
    BUSHNELL, GW
    HUNTER, RG
    MCFARLAN.JJ
    DIXON, KR
    CANADIAN JOURNAL OF CHEMISTRY, 1972, 50 (22): : 3694 - &
  • [39] THIOETHER COMPLEXES WITH PALLADIUM(II) AND PLATINUM(II)
    SPANGLER, NJ
    GRANT, GJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 203 : 174 - INOR
  • [40] DIHYDRIDE COMPLEXES OF PLATINUM(II) AND PALLADIUM(II)
    KUDO, K
    HIDAI, M
    UCHIDA, Y
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 56 (AUG1) : 413 - 418
12345