Synthesis and characterization of 2-dimethylaminoethyl thiolate complexes of palladium(II) and platinum(II)

被引：0

作者：

Dey, S

Jain, VK ^{[1
]}

Knoedler, A

Kaim, W

机构：

[1] Bhabha Atom Res Ctr, Novel Mat & Struct Chem Div, Bombay 400085, Maharashtra, India

[2] Univ Stuttgart, Inst Anorgan Chem, D-70569 Stuttgart, Germany

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2003年 / 42卷 / 09期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of Na2PdCl4 with Me2NCH2CH2SH.HCl in methanol affords a trimeric complex [PdCl(SCH2CH2NMe2)](3). Treatment of [M2Cl2(mu-Cl)(2)(PR3)(2)] (M = Pd or Pt) with Me2NCH2CH2SH.HCl in the presence of NaHCO3 Yields complexes of the type [MCl(SCH2CH2NMe2)(PR3)](n) (n = 1 or 2). These complexes have been isolated as monomeric species containing chelating thiolate ligands. In some cases, with more basic phosphines, binuclear complexes (n = 2) containing bridging thiolate ligands are also formed. All complexes have been characterized by elemental analysis and NMR spectroscopy. The structure of [PdCl(SCH2CH2NMe2)(PPh3)] (2c) has been established by X-ray crystallography.

引用

页码：2339 / 2343

页数：5

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