μ-2,2′,6,6′-Tetramethyl-4,4′-bipyridine-κ2N1:N1′-bis[(diethylenetriamine-κ3N,N′,N")palladium(II)] tetranitrate

被引：1

作者：

Seidel, Ruediger W. ^{[1
]}

Oppel, Iris M. ^{[2
]}

机构：

[1] Lehrstuhl Analyt Chem, D-44780 Bochum, Germany

[2] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52074 Aachen, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2011年 / 67卷

关键词：

PILLARED COORDINATION CAGES; DISCRETE STACKING; COMPLEXES; 4,4'-BIPYRIDINE; SUBSTITUTION; MOLECULES; PD;

D O I：

10.1107/S0108270111017586

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Pd-2(C4H13N3)(2)(C14H16N2)](NO3)(4), comprises discrete tetracationic dumbbell-type dinuclear complex molecules and noncoordinating nitrate anions. Two Pd(dien)(2+) moieties (dien is diethylenetriamine) are joined by the rigid linear exo-bidentate bridging 2,2',6,6'-tetramethyl-4,4'-bipyridine ligand to form the dinuclear complex, which lies across a centre of inversion in the space group P2(1)/n, so that the rings in the 2,2',6,6'-tetramethyl-4,4'-bipyridine bridging ligand are parallel. In the crystal, the primary and secondary amino groups of the dien ligand act as hydrogen-bond donors towards the nitrate anions to form a three-dimensional hydrogen-bond network.

引用

页码：M199 / M201

页数：3

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