μ-4,4′-bipyridine-κ2N:N-bis[triaqua(4,4′-bipyridine-κ2N,N′)[1,3-phenylenedi(oxyacetato)-κO]cobalt(II)] 4,4′-bipyridine heptahydrate

被引：2
|
作者：
Gao, S
Liu, JW
Huo, LH
Zhao, H
Ng, SW [1 ]
机构：
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Heilongjiang Univ, Coll Chem & Mat Sci, Harbin 150080, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷
关键词：
D O I：
10.1107/S1600536804024535
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The reaction of cobalt(II) diacetate, disodium 1,3-phenyldi(oxyacetate) and 4,4'-bipyridine in water at neutral pH affords the title compound, [CO2(C10H8O6)(2)(C10H8N2)(3)(H2O)(6)].C10H8N2.7H(2)O. The dinuclear complex is generated from a unique half-molecule by twofold symmetry; it contains a bridging 4,4'-bipyridine molecule connected to two cobalt(II) atoms, each of which is covalently bonded to a carboxylate unit, another 4,4'-bipyridine molecule and three water molecules in octahedral geometry. The non-coordinated 4,4'-bipyridine molecule is stacked over the bridging 4,4'-bipyridine molecule at a separation of about 3.5 Angstrom, and accepts hydrogen bonds at each N atom from coordinated water molecules.
引用
收藏
页码：M1590 / M1592
页数：3
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