catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ2N:N′] bis(perchlorate) 4,4′-bipyridine disolvate dihydrate]

被引：1
|
作者：
Nettleman, Joseph H. [1 ]
LaDuca, Robert L. [1 ]
机构：
[1] Michigan State Univ, Dept Chem, Lyman Briggs Coll, E Lansing, MI 48825 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536808035125
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, {[Co(C10H8N2)(H2O)4](ClO4)(2)center dot-2C(10)H(8)N(2) center dot 2H(2)O}(n), slightly distorted octahedrally coordinated Co-II ions situated on inversion centers are linked into polycationic chains through 4,4'-bipyridine tethering ligands. These are connected into supramolecular layers by hydrogen bonding involving aqua ligands, perchlorate anions and uncoordinated water molecules. A twofold interpenetrated primitive cubic supramolecular network is formed by the interaction of pseudo-layers by hydrogen bonding between aqua ligands and unligated 4,4 '-bipyridine molecules.
引用
收藏
页码：M1485 / U1291
页数：13
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