AgF-Mediated Electrophilic Amination of Alkoxyarylsilanes with Azodicarboxylates

被引：3
|
作者：
Zhang, Qian [1 ]
Deng, Shijun [1 ]
Li, Dong [1 ]
Shimokawa, Jun [2 ]
Yorimitsu, Hideki [2 ]
机构：
[1] Hubei Univ Technol, Sch Mat & Chem Engn, New Mat & Green Mfg Talent Intro & Innovat Demons, Wuhan 430068, Peoples R China
[2] Kyoto Univ, Dept Chem, Grad Sch Sci, Sakyo Ku, Kyoto 6068502, Japan
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2022年 / 17卷 / 05期
关键词：
amination; alkoxysilane; silver; azodicarboxylate; arylamine; CROSS-COUPLING REACTIONS; SIMPLE ETHERS; N-ARYLATION; COPPER; PICOLINAMIDES; ARENES; CARBON; ACIDS;
D O I：
10.1002/asia.202101345
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A facile and efficient AgF-mediated electrophilic amination of alkoxyarylsilanes with azodicarboxylates was developed. The reaction proceeds in green solvent under simple and mild conditions to generate the corresponding aryl hydrazines. AgF acts both as a stoichiometric fluoride source and a reagent for transmetalation to the arylsilver intermediate that eventually reacts with azodicarboxylates to provide aryl hydrazines.
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页数：6
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