AgF-Mediated Electrophilic Amination of Alkoxyarylsilanes with Azodicarboxylates

被引：3

作者：

Zhang, Qian ^{[1
]}

Deng, Shijun ^{[1
]}

Li, Dong ^{[1
]}

Shimokawa, Jun ^{[2
]}

Yorimitsu, Hideki ^{[2
]}

机构：

[1] Hubei Univ Technol, Sch Mat & Chem Engn, New Mat & Green Mfg Talent Intro & Innovat Demons, Wuhan 430068, Peoples R China

[2] Kyoto Univ, Dept Chem, Grad Sch Sci, Sakyo Ku, Kyoto 6068502, Japan

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2022年 / 17卷 / 05期

关键词：

amination; alkoxysilane; silver; azodicarboxylate; arylamine; CROSS-COUPLING REACTIONS; SIMPLE ETHERS; N-ARYLATION; COPPER; PICOLINAMIDES; ARENES; CARBON; ACIDS;

D O I：

10.1002/asia.202101345

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile and efficient AgF-mediated electrophilic amination of alkoxyarylsilanes with azodicarboxylates was developed. The reaction proceeds in green solvent under simple and mild conditions to generate the corresponding aryl hydrazines. AgF acts both as a stoichiometric fluoride source and a reagent for transmetalation to the arylsilver intermediate that eventually reacts with azodicarboxylates to provide aryl hydrazines.

引用

页数：6

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