Crystal structure of 1,1′-(pyridine-2,6-diyl)bis[N-(pyridin-2-ylmethyl)methanaminium] dichloride dihydrate

被引:0
|
作者
Merabet, Layachi [1 ,2 ]
Tasse, Marine [1 ]
Mallet-Ladeira, Sonia [1 ,3 ]
Kaboub, Lakhemici [2 ]
Malfant, Isabelle [1 ]
机构
[1] UPR CNRS 8241, Lab Chim Coordinat, 205 Route Narbonne, F-31077 Toulouse, France
[2] Univ Ferhat Abbas Setif 1, Lab Chem Mol Engn & Nanostruct, Dept Chem, Fac Sci, Setif 19000, Algeria
[3] Inst Chim Toulouse UAR CNRS 2599, 118 Route Narbonne, F-31062 Toulouse 09, France
关键词
crystal structure; hydrogen bonding; pi-pi interactions; CARBOXAMIDE LIGANDS; RUTHENIUM NITROSYL; NO; DELIVERY; LIGHT; NITROGEN;
D O I
10.1107/S205698902101183X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C19H23N52+center dot 2Cl(-)center dot 2H(2)O, the two pyridine side arms are not coplanar, with the terminal pyridine rings subtending a dihedral angle of 26.45 (6)degrees. In the crystal, hydrogen bonds, intermolecular C-H center dot center dot center dot Cl contacts and a weak C-H center dot center dot center dot O interaction connect the molecule with neighbouring chloride counter-anions and lattice water molecules. The crystal packing also features by pi-pi interactions with centroid-centroid distances of 3.4864 (12) and 3.5129 (13) angstrom.
引用
收藏
页码:1296 / +
页数:8
相关论文
共 50 条
  • [41] Synthesis, characterization, crystal structure, hirshfeld surface analysis and DFT calculations of N-(pyridin-2-ylmethyl)furan-2-carboxamide and its molecular docking
    M. Mohanbabu
    P. N. Sathishkumar
    N. S. P. Bhuvanesh
    R. Karvembu
    K. Saravanan
    E. Vinoth
    S. Aravindhan
    Journal of Materials Science: Materials in Electronics, 2022, 33 : 9616 - 9628
  • [42] μ-1,1′-methylenedi-1H-imidazole-κ2N3:N3′-bis[aqua(pyridine-2,6-dicarboxylato)copper(II)] tetrahydrate
    Dong, GY
    Cui, GH
    Wang, SC
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M606 - M607
  • [43] 1,1′-(Butane-1,4-diyl)bis(1H-benzimidazol-3-ium) diiodo(pyridine-2,6-dicarboxylato-κ3O,N,O′)mercurate(II)
    Bao, TH
    Hou, ZY
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M801 - M803
  • [44] Crystal structure of (7-{[bis(pyridin-2-ylmethyl)-amino-κ3 N,N′,N"]methyl}-5-chloroquinolin-8-ol)dibromidozinc(II)
    Kubono, Koji
    Kashiwagi, Yukiyasu
    Tani, Keita
    Yokoi, Kunihiko
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2022, 78 : 326 - +
  • [45] Synthesis and Characterisation of 1,1′-{[3,5-Bis(dodecyloxy-carbonyl)-4-(thiophen-3-yl)-1,4-dihydropyridine-2,6-diyl]bis(methylene)}bis(pyridin-1-ium) Dibromide
    Rucins, Martins
    Pajuste, Karlis
    Plotniece, Aiva
    Pikun, Nadiia
    Rodik, Roman
    Vyshnevskiy, Sergiy
    Sobolev, Arkadij
    MOLBANK, 2022, 2022 (01)
  • [46] The crystal structure of (N-([1,1':4',1''.-terphenyl]4,4'-diethyl)-2-(bis(pyridin-2-ylmethyl)amino) acetamide-K4N,N,N'', O)tri(nitrato-kO, O') samarium(III) - methanol - acetonitrile (1/1/1), C40H39SmN8O14
    Wang, Hai-Ping
    Zhang, Ci-Mao
    Huang, Guo-Peng
    Liang, Jia-Jun
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2023, 238 (05): : 813 - 815
  • [47] Synthesis, structure, and properties of {N,N′-bis[2-(1-pyrazolyl)ethyl]pyridine-2,6-dicarboxamido}copper(II)
    Chavez, FA
    Olmstead, MM
    Mascharak, PK
    INORGANICA CHIMICA ACTA, 1998, 269 (02) : 269 - 273
  • [48] Synthesis and Spectral Studies of Nickel(II) Complex of 2,6-Bis [N-(1,1′-Dimethyl-2′-Hydroxy)Carbamoyl]Pyridine
    Luo Shi-xia
    Chen Xiao-jing
    Zhu Huai-wu
    Zhang Xiao-yi
    Wei Gang
    SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32 (03) : 805 - 808
  • [50] Synthesis, Crystal Structure and Insecticidal Activity of N-(pyridin-2-ylmethyl)-1-phenyl-1,4,5,6,7,8-hexahydrocyclohepta [c]pyrazole-3-carboxamide
    Deng Xi-Le
    Zhou Xiao-Mao
    Wang Zan-Yong
    Rui Chang-Hui
    Yang Xin-Ling
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 37 (04) : 551 - 556